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Record W4396584146 · doi:10.20431/2349-0403.1101001

Rapid Screening of Natural Liquid Sweeteners by Capillary Electrophoresis

2024· article· en· W4396584146 on OpenAlexfundno aff
S. H. Kirby, Zafar Iqbal, Edward P. C. Lai, Tyler J. Avis

Bibliographic record

VenueInternational journal of advanced research in chemical sciences · 2024
Typearticle
Languageen
FieldChemistry
TopicAnalytical Chemistry and Chromatography
Canadian institutionsnot available
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsCapillary electrophoresisChromatographyChemistry

Abstract

fetched live from OpenAlex

Capillary electrophoresis (CE) is an instrumental method of chemical analysis that has been developed for the rapid screening of liquid sweeteners (corn syrups, honeys, maple syrups and nectars) from different geographic regions.CE can separate organic compounds in each sweetener sample based on their charge-to-size ratios in a background electrolyte (BGE) solution.Ultraviolet (UV) light absorption can detect the separated compounds for quantitation.Electrophoretic mobility values were determined for all the CE-UV peaks to identify whether flavonoids (e.g., quercetin) and phenolic compounds (e.g., rutin) were present in the sweetener.A novel approach was also developed to perform CE-UV analysis by spiking honeys in the background electrolyte.Due to an increase of the viscosity, both the electroosmotic flow (as indicated by a neutral marker) and the electrophoretic mobility of polydopamine-coated magnetic nanoparticles were decreased by approximately 50%.The electrical conductance was also decreased by approximately 30% due to a higher BGE solution viscosity.These results have demonstrated that CE-UV is a promising technique for the rapid screening of natural liquid sweeteners to detect adulteration by corn syrup.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.003

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0010.000
Science and technology studies0.0000.000
Scholarly communication0.0010.000
Open science0.0000.000
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.032
GPT teacher head0.375
Teacher spread0.343 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2024
Admission routes1
Has abstractno

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