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Record W4396619536 · doi:10.1002/smll.202401391

Synergistic Cathode Design for High‐Performance Dual‐Salt Magnesium/Lithium‐Ion Batteries Using 2D/2D 1T/2H‐MoS<sub>2</sub>@Ti<sub>3</sub>C<sub>2</sub>T<sub><i>x</i></sub> MXene Nanocomposite

2024· article· en· W4396619536 on OpenAlexaff
Jalal Rahmatinejad, Xudong Liu, Bahareh Raisi, Zhibin Ye

Bibliographic record

VenueSmall · 2024
Typearticle
Languageen
FieldMaterials Science
TopicMXene and MAX Phase Materials
Canadian institutionsConcordia University
Fundersnot available
KeywordsCathodeMaterials scienceAnodeLithium (medication)NanocompositeMagnesiumEnergy storageChemical engineeringIonNanotechnologyElectrodeChemistryMetallurgyOrganic chemistry

Abstract

fetched live from OpenAlex

Abstract Magnesium‐ion batteries (MIBs) and dual‐salt magnesium/lithium‐ion batteries (MLIBs) have emerged as promising contenders for next‐generation energy storage. In contrast to lithium metal anode in lithium metal batteries, magnesium metal anode in MIBs and MLIBs presents a safer alternative due to the limited dendrite growth and higher volumetric capacity, along with higher natural abundance. This study explores a MLIB configuration with a novel cathode design by employing a 2D/2D nanocomposite of 1T/2H mixed phase MoS 2 and delaminated Ti 3 C 2 T x MXene (1T/2H‐MoS 2 @MXene) to address challenges associated with slow kinetics of magnesium ions during cathode interactions. This cathode design takes advantage of the high electrical conductivity of Ti 3 C 2 T x MXene and the expanded interlayer spacing with enhanced conductivity of the 1T metallic phase in 1T/2H mixed phase MoS 2 . Through a designed synthesis method, the resulting nanocomposite cathode maintains structural integrity, enabling the stable and reversible storage of dual Mg 2+ and Li + ions. The nanocomposite cathode demonstrates superior performance in MLIBs compared to individual components (253 mAh g −1 at 50 mA g −1 , and 36% of capacity retention at 1,000 mA g −1 ), showcasing short ion transport paths and fast ion storage kinetics. This work represents a significant advancement in cathode material design for cost‐effective and safe MLIBs.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.004
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Science and technology studies, Scholarly communication, Insufficient payload (model declined to judge)
Consensus categoriesMeta-epidemiology (narrow)
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.025
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0040.000
Meta-epidemiology (narrow)0.0020.002
Meta-epidemiology (broad)0.0020.001
Bibliometrics0.0010.001
Science and technology studies0.0020.001
Scholarly communication0.0020.002
Open science0.0010.001
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0000.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.032
GPT teacher head0.247
Teacher spread0.215 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; both teacher heads agree on what is shown here.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations13
Published2024
Admission routes1
Has abstractyes

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