Steering Interfacial Renovation with Highly Electronegative Cl Modulated Trinity Effect for Exceptional Durable Zinc Anode
Why this work is in the frame
A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.
Bibliographic record
Abstract
Abstract The poor anode/electrolyte interface triggered by abysmal dendritic growth and hydrogen evolution reactions (HER) hinders the development of aqueous zinc‐ion batteries (AZIBs). Here, a highly efficient electrolyte is formulated with sucralose (Sucral) additive to refresh solvated structure and steer interfacial renovation, for building highly electronegative Cl‐modulated trinity effect in the bulk‐interface between electrolyte and electrode. Experiment results and theoretical studies jointly reveal that Sucral with highly zincophilic and hydrophilic hydroxyl groups can remodel primary Zn 2+ solvation shell and interrupt strong H‐bond network from H 2 O molecules, thus boosting fast de‐solvation and restricting undesirable HER. Simultaneously, three highly electronegative chlorides in the adsorbed Sucral possessing hydrophobic features can enable a H 2 O‐poor electric double‐layer (EDL), thus remodeling the Zn surface against corrosion. Additionally, it realizes preferential exposure of the Zn (002) plane for helping uniform interfacial deposition. The synergy of the above factors achieves a prolonged lifespan of 3000 h (1.0 mA cm −2 , 1.0 mAh cm −2 ), much better than that with Sucrose (Suc) electrolyte. The Zn//V 2 O 5 full cell at 5 A g −1 also maintains enhanced stability of 1500 cycles with 160 mAh g −1 .
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.001 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it