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Record W4396856771 · doi:10.1016/j.chemgeo.2024.122149

Dating metamorphic processes and identifying 87Sr/86Sr inheritance using volume-coupled Rb/Sr geochronology and geochemistry of in situ white mica: A demonstration with HP/LT rocks from Syros, Greece

2024· article· en· W4396856771 on OpenAlexaff
Christopher J. Barnes, Thomas Zack, Michał Bukała, Delia Rösel, Chris Mark, David Schneider

Bibliographic record

VenueChemical Geology · 2024
Typearticle
Languageen
FieldEarth and Planetary Sciences
TopicGeological and Geochemical Analysis
Canadian institutionsUniversity of Ottawa
Fundersnot available
KeywordsGeochronologyGeologyMetamorphic rockMicaGeochemistryPaleontology

Abstract

fetched live from OpenAlex

High-pressure/low-temperature rocks from two well-studied outcrops of the Cycladic Blueschist Unit on Syros are used to demonstrate the advantages of volume-coupled 87 Rb/ 87 Sr geochronology and geochemistry of in situ white mica. Single-spot Rb/Sr dates are interpreted based on the microstructural position of white mica combined with its chemical information, and the results are discussed within the tectonic framework of the island. The first outcrop on Katerghaki cape exposes rigid blocks of foliated eclogite within well-foliated blueschist, whereas the second outcrop on Delfini peninsula comprises massive eclogitic blocks, likely of metasomatic origin, hosted within blueschist that are interlayered with white mica schists. The rheological contrasts exhibited in both outcrops preserve (near-)peak HP/LT metamorphism/metasomatism (eclogites) followed by retrogression and deformation in lower P-T conditions (blueschist, micaschist). The white mica in eclogite from both outcrops are in equilibrium with the HP/LT mineral assemblages, do not show chemical zoning nor systematic chemical variations, and yield uniform single-spot Rb/Sr dates. Weighted averages of the Rb/Sr dates are 48.2 ± 3.7 Ma (MSWD: 0.9, n: 34; Katerghaki) and 44.5 ± 3.1 Ma (MSWD: 0.7, n: 28; Delfini), interpreted as (near-)peak HP/LT metamorphism and metasomatism , respectively, overlapping with published garnet Lu Hf and Sm Nd geochronology of the corresponding outcrops. White mica in the Katerghaki blueschist and the Delfini micaschist exhibit significant chemical zoning and correlations of Ti with major and trace elements (Al, Fe , Mg, Rb, Sr, Zn, Ba, Nb). Weighted age averages were calculated from Rb/Sr dates corresponding to high-Ti and low-Ti white mica compositions. The blueschist yields ages of 56.0 ± 10.6 Ma (MSWD: 2.2, n: 20/80) and 36.3 ± 2.1 Ma (MSWD: 0.9, n: 20/80), whereas the micaschist produced ages of 43.7 ± 3.5 Ma (MSWD: 0.5, n: 14/53) and 31.9 ± 2.7 Ma (MSWD: 1.0, n: 13/53), respectively. These results are interpreted to resolve the timing of fluid-mediated isotopic re-equilibration of white mica during deformation and retrogression (low-Ti), and reflect 87 Sr/ 86 Sr inheritance from the earlier HP/LT history (high-Ti). Overall, the results demonstrate that coupling 87 Rb/ 87 Sr geochronology with geochemistry of white mica in situ is advantageous for evaluating Rb/Sr datasets that may possess a single mica population (eclogites) or are affected by 87 Sr/ 86 Sr inheritance (blueschist, micaschist) in order to interpret geologically meaningful ages.

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How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.361
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.001
Science and technology studies0.0000.001
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.016
GPT teacher head0.211
Teacher spread0.195 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations11
Published2024
Admission routes1
Has abstractyes

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