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Random singlet-like state in the dimer-based triangular antiferromagnet <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mrow><mml:msub><mml:mi>Ba</mml:mi><mml:mn>6</mml:mn></mml:msub><mml:msub><mml:mi mathvariant="normal">Y</mml:mi><mml:mn>2</mml:mn></mml:msub><mml:msub><mml:mi>Rh</mml:mi><mml:mn>2</mml:mn></mml:msub><mml:msub><mml:mi>Ti</mml:mi><mml:mn>2</mml:mn></mml:msub><mml:msub><mml:mi mathvariant="normal">O</mml:mi><mml:mrow><mml:mn>17</mml:mn><mml:mo>−</mml:mo><mml:mi>δ</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math>

2024· article· lv· W4399302359 on OpenAlexaff
Wonjun Lee, Sungwon Yoon, Sungmin Jeon, Yipeng Cai, Kenji Kojima, Loi T. Nguyen, R. J. Cava, Kwang-Yong Choi, Suheon Lee

Bibliographic record

VenuePhysical Review Research · 2024
Typearticle
Languagelv
FieldPhysics and Astronomy
TopicAdvanced Condensed Matter Physics
Canadian institutionsUniversity of British ColumbiaTRIUMF
FundersBasic Energy SciencesInstitute for Basic ScienceCollege of Science, Sungkyunkwan UniversityNational Research Foundation of KoreaU.S. Department of EnergyOffice of Science
KeywordsAntiferromagnetismPhysicsCrystallographyCondensed matter physicsChemistry

Abstract

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We present the magnetic, thermodynamic, and muon spin relaxation (<a:math xmlns:a="http://www.w3.org/1998/Math/MathML"><a:mrow><a:mi>μ</a:mi><a:mi>SR</a:mi></a:mrow></a:math>) results of the dimer-based triangular antiferromagnet <b:math xmlns:b="http://www.w3.org/1998/Math/MathML"><b:mrow><b:msub><b:mi>Ba</b:mi><b:mn>6</b:mn></b:msub><b:msub><b:mi mathvariant="normal">Y</b:mi><b:mn>2</b:mn></b:msub><b:msub><b:mi>Rh</b:mi><b:mn>2</b:mn></b:msub><b:msub><b:mi>Ti</b:mi><b:mn>2</b:mn></b:msub><b:msub><b:mi mathvariant="normal">O</b:mi><b:mrow><b:mn>17</b:mn><b:mo>−</b:mo><b:mi>δ</b:mi></b:mrow></b:msub></b:mrow></b:math>. The magnetic susceptibility data show the sub-Curie-Weiss behavior <e:math xmlns:e="http://www.w3.org/1998/Math/MathML"><e:mrow><e:mi>χ</e:mi><e:mrow><e:mo>(</e:mo><e:mi>T</e:mi><e:mo>)</e:mo></e:mrow><e:mo>∝</e:mo><e:msup><e:mi>T</e:mi><e:mrow><e:mo>−</e:mo><e:msub><e:mi>α</e:mi><e:mi>χ</e:mi></e:msub></e:mrow></e:msup></e:mrow></e:math> below 100 K, suggesting random magnetism. The isothermal magnetization results reveal the presence of weakly interacting structural orphan spins about <f:math xmlns:f="http://www.w3.org/1998/Math/MathML"><f:mrow><f:mn>6.1</f:mn><f:mo>%</f:mo></f:mrow></f:math> at 2 K, arising from the oxygen deficiency. The comprehensive <g:math xmlns:g="http://www.w3.org/1998/Math/MathML"><g:mrow><g:mi>μ</g:mi><g:mi>SR</g:mi></g:mrow></g:math> experiments exhibit the coexisting relaxing and nonrelaxing components along with the thermally activated behavior in the muon spin relaxation rate, reflecting the fluctuating orphan spins in the dimer singlet background. In addition, we observe the scaling behavior of <h:math xmlns:h="http://www.w3.org/1998/Math/MathML"><h:mrow><h:mi>M</h:mi><h:mo>(</h:mo><h:mi>H</h:mi><h:mo>,</h:mo><h:mi>T</h:mi><h:mo>)</h:mo></h:mrow></h:math> in <i:math xmlns:i="http://www.w3.org/1998/Math/MathML"><i:mrow><i:mi>H</i:mi><i:mo>/</i:mo><i:mi>T</i:mi></i:mrow></i:math> and <j:math xmlns:j="http://www.w3.org/1998/Math/MathML"><j:mrow><j:msub><j:mi>P</j:mi><j:mi>z</j:mi></j:msub><j:mrow><j:mo>(</j:mo><j:mi>t</j:mi><j:mo>)</j:mo></j:mrow></j:mrow></j:math> in <k:math xmlns:k="http://www.w3.org/1998/Math/MathML"><k:mrow><k:mi>t</k:mi><k:mo>/</k:mo><k:msub><k:mi>H</k:mi><k:mtext>LF</k:mtext></k:msub></k:mrow></k:math> with the scaling exponents <l:math xmlns:l="http://www.w3.org/1998/Math/MathML"><l:mrow><l:msub><l:mi>α</l:mi><l:mi>χ</l:mi></l:msub><l:mo>=</l:mo><l:msub><l:mi>α</l:mi><l:mtext>M</l:mtext></l:msub><l:mo>=</l:mo><l:mn>0.75</l:mn></l:mrow></l:math> and <m:math xmlns:m="http://www.w3.org/1998/Math/MathML"><m:mrow><m:msub><m:mi>α</m:mi><m:mi>μ</m:mi></m:msub><m:mo>=</m:mo><m:mn>0.72</m:mn></m:mrow></m:math>, respectively, but not for the magnetic specific heat data. The failure of the scaling relation in <n:math xmlns:n="http://www.w3.org/1998/Math/MathML"><n:mrow><n:msub><n:mi>C</n:mi><n:mtext>m</n:mtext></n:msub><n:mrow><n:mo>(</n:mo><n:mi>H</n:mi><n:mo>,</n:mo><n:mi>T</n:mi><n:mo>)</n:mo></n:mrow><n:mo>/</n:mo><n:mi>T</n:mi></n:mrow></n:math> implies low-energy excitations dressed by the conventional orphan spins. Based on these observations, we find that the magnetic ground state resembles random singlets and discuss the possible configurations of the spin dimer unit <o:math xmlns:o="http://www.w3.org/1998/Math/MathML"><o:mrow><o:msub><o:mi>Rh</o:mi><o:mn>2</o:mn></o:msub><o:msub><o:mi mathvariant="normal">O</o:mi><o:mn>9</o:mn></o:msub></o:mrow></o:math>. Our results shed light on the role of quenched disorder in the dimer-based frustrated magnets. Published by the American Physical Society 2024

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How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.013
metaresearch head score (Gemma)0.007
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Meta-epidemiology (broad), Science and technology studies, Scholarly communication, Open science, Research integrity, Insufficient payload (model declined to judge)
Consensus categoriesMeta-epidemiology (narrow), Science and technology studies, Open science, Research integrity, Insufficient payload (model declined to judge)
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: none
Teacher disagreement score0.892
Threshold uncertainty score0.999

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0130.007
Meta-epidemiology (narrow)0.0050.011
Meta-epidemiology (broad)0.0020.011
Bibliometrics0.0040.010
Science and technology studies0.0090.010
Scholarly communication0.0100.008
Open science0.0140.011
Research integrity0.0090.012
Insufficient payload (model declined to judge)0.8620.014

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.027
GPT teacher head0.284
Teacher spread0.256 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; both teacher heads agree on what is shown here.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

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Citations8
Published2024
Admission routes1
Has abstractyes

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