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Record W4399353923 · doi:10.1002/adma.202403632

Accelerated Discovery of (TiZrHf)<sub><i>x</i></sub>(NbTa)<sub>1−</sub><sub><i>x</i></sub> High‐Entropy Alloys With Superior Thermal Stability and a New Crystallization Mechanism

2024· article· en· W4399353923 on OpenAlexafffund
Changjun Cheng, Renfei Feng, Tianyi Lyu, Yu Zou

Bibliographic record

VenueAdvanced Materials · 2024
Typearticle
Languageen
FieldEngineering
TopicHigh Entropy Alloys Studies
Canadian institutionsCanadian Light Source (Canada)University of Toronto
FundersNatural Sciences and Engineering Research Council of CanadaCanada First Research Excellence Fund
KeywordsMaterials scienceCrystallizationNanocrystalline materialAnnealing (glass)Thermal stabilityAlloyHigh entropy alloysAmorphous solidCrystallographyGrain growthGrain sizeNanocompositeChemical engineeringChemical physicsThermodynamicsNanotechnologyMetallurgy

Abstract

fetched live from OpenAlex

Abstract Nanocrystalline (nc) metals are generally strong yet thermally unstable, rendering them difficult to process and unsuitable for use, particularly at elevated temperatures. Nc multicomponent and high‐entropy alloys (HEAs) are found to offer enhanced thermal stability but only in a few empirically discovered systems out of a vast compositional space. In response, this work develops a combinatorial strategy to accelerate the discovery of nc‐(TiZrHf) x (NbTa) 1− x alloy library with distinct thermal stability, in terms of phases and grain sizes. Based on synchrotron X‐ray diffraction and electron microscopy characterizations, a phase transition is observed from amorphous–crystalline nanocomposites to a body‐centered cubic (bcc) phase upon annealing. With increased NbTa content (decreased x value), the system tends to achieve thermally stable dual bcc phases upon annealing; in contrast, alloys with increased TiZrHf content ( x &gt; 0.6) maintain a single‐composition nanocomposite state, impeding crystallization and grain growth. This investigation not only broadens the understanding of thermal stability but also delves into the onset of crystallization in HEA systems.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.018
Threshold uncertainty score0.999

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.002
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.010
GPT teacher head0.205
Teacher spread0.195 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations13
Published2024
Admission routes2
Has abstractyes

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