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Record W4399926685 · doi:10.1029/2024gc011485

Crust‐Derived CO<sub>2</sub> Production From a Shallow Pluton in Limestone Is Driven by Metamorphic Decarbonation, Not Assimilation

2024· article· en· W4399926685 on OpenAlexafffundabout
Rebecca Morris, Dante Canil

Bibliographic record

VenueGeochemistry Geophysics Geosystems · 2024
Typearticle
Languageen
FieldEarth and Planetary Sciences
TopicGeological and Geochemical Analysis
Canadian institutionsUniversity of Victoria
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsPlutonCrustMetamorphic rockGeologyAssimilation (phonology)GeochemistryEarth sciencePetrologyPaleontologyTectonics

Abstract

fetched live from OpenAlex

Abstract Traditionally, it is assumed that contributions of crust‐derived CO 2 emissions at arc settings are minor, but this requires well‐constrained field studies to determine the extent of magma‐carbonate reaction and concomitant C released. The Jurassic Bonanza arc on Vancouver Island (Canada) was built on a Triassic limestone platform and makes for an ideal setting to examine arc magma‐carbonate interactions beneath an island arc. We examine how km‐scale magma bodies might react with carbonate from a well‐constrained study of a gabbro pluton that intrudes limestone. The pluton shows muted to nil carbonate interaction preserving primary igneous 87 Sr/ 86 Sr values (∼0.703) except for a thin (&lt;2 m wide) marginal gabbro (∼0.706) in contact with a decarbonized metamorphic aureole. A lack of 87 Sr/ 86 Sr or δ 18 O cpx enrichment in gabbro ∼10 to &gt;1,000 m from the contact suggests that any reaction with limestone wallrock is limited to at most the outer ∼10 m of the pluton. More enhanced magma‐carbonate interaction and CO 2 production occurs via a network of shallow dikes and sills (&lt;0.2 GPa) compared to deeper plutons, consistent with experimental data showing increased carbonate assimilation at shallower depths (≤0.5 GPa). Plutons are an important heat source to release CO 2 from carbonate wallrock by contact metamorphism, where &gt;89% of crust‐derived CO 2 is liberated by wallrock decarbonation and &lt;11% is liberated by magma that assimilated limestone. Nonetheless, we show that neither magmatic nor metamorphic crust‐derived CO 2 contributions compare to mantle‐derived CO 2 . Our study places realistic and quantitative limits on arc‐derived CO 2 from upper crustal limestone sources.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Insufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.119
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.011
GPT teacher head0.200
Teacher spread0.189 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations2
Published2024
Admission routes3
Has abstractyes

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