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Record W4400332894 · doi:10.5539/ijc.v16n2p62

Ionic Buswell’s Equation for Biohydrogen

2024· article· en· W4400332894 on OpenAlexvenueno aff
Pong Kau Yuen, Cheng Man Diana Lau

Bibliographic record

VenueInternational Journal of Chemistry · 2024
Typearticle
Languageen
FieldChemistry
TopicSynthesis and biological activity
Canadian institutionsnot available
Fundersnot available
KeywordsChemistryHydrazoneOximeAntimicrobialDiastereomerLactoneStereochemistryCombinatorial chemistryOrganic chemistry

Abstract

fetched live from OpenAlex

Molecular hydrogen (H2) can be generated by thermochemical, electrochemical, photochemical, or biochemical methods. Biohydrogen, specifically, can be produced by biochemical methods such as dark fermentation and two-stage anaerobic digestion, which may be represented by Buswell’s equation. Although the molecular Buswell’s equation for biohydrogen has been explored, the study of ionic Buswell’s equation for biohydrogen has rarely been considered. This article shows that an ionic Buswell’s equation for biohydrogen can be balanced and deduced by the proton method when an empirical formula of organic matter is given. The relationships between the mean oxidation number of organic carbons, number of transferred electrons, and quantity of biohydrogen are established. Furthermore, using the mean oxidation number of organic carbons as a metric, the number of transferred electrons, quantity of biohydrogen, ratio of quantity of biohydrogen to quantity of organic carbons, and theoretical biohydrogen potential can be determined through the derived mathematical equations by any given empirical or structural formula.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.003
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Theoretical or conceptual · Consensus signal: Theoretical or conceptual
GenreCandidate signal: Empirical · Consensus signal: none
Teacher disagreement score0.023
Threshold uncertainty score0.078

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.003
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0020.002
Science and technology studies0.0010.002
Scholarly communication0.0010.005
Open science0.0030.001
Research integrity0.0020.003
Insufficient payload (model declined to judge)0.0230.008

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.030
GPT teacher head0.291
Teacher spread0.261 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designTheoretical or conceptual
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2024
Admission routes1
Has abstractyes

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