A Limited Evaluation of the Applicability of NACE MR0175/ISO 15156 H2S Limits to Supercritical CO2 Pipelines
Bibliographic record
Abstract
In an earlier paper one of the authors raised the question of whether the hydrogen sulfide (H2S) partial pressure threshold of 0.05 psia (0.3 kPa) for cracking of steels from sulfide stress cracking is pertinent to dense phase carbon dioxide (CO2) systems in which there is no free gas phase. This paper presents a limited test of the pertinence of this threshold value in Supercritical CO2. Autoclave tests of four-point bend beam specimens of API 5L Grade X80 line pipe steel at 0.05 psia (0.3 kPa) and 0.20 psia (1.38 kPa) H2S were performed and the samples were examined after testing for cracking. In addition, the test conditions were modeled with the OLI Studio software to determine the H2S fugacities and H2S concentrations in the brine phase. No cracking was found after 30 d of exposure.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.001 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".