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Record W4401646020 · doi:10.1002/smtd.202400753

Adsorption Dynamics of Disodium Octaborate Tetrahydrate on Clay Minerals: Implications for Construction Wood Protection

2024· article· en· W4401646020 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueSmall Methods · 2024
Typearticle
Languageen
FieldEngineering
TopicWood Treatment and Properties
Canadian institutionsÉcole de Technologie SupérieureUniversité du Québec à Montréal
FundersNatural Sciences and Engineering Research Council of CanadaMitacsCentre québécois sur les matériaux fonctionnels
KeywordsAdsorptionTetrahydrateMoistureInductively coupled plasmaAtomic force microscopyMaterials scienceSpectroscopyBoronMineralogyAnalytical Chemistry (journal)ChemistryComposite materialEnvironmental chemistryNanotechnologyCrystallographyCrystal structurePhysics

Abstract

fetched live from OpenAlex

The wood preservative disodium octaborate tetrahydrate (DOT) migration is studied in clay. Using boron analysis by inductively coupled plasma optical emission spectroscopy (ICP-OES), DOT spatial and temporal dynamics are surveyed to show how DOT permeates into the wood and the clay using concentration profiles as a function of depth, initial wood moisture, and direction of filling. Atomic force microscopy and chemical imaging using photoinduced force microscopy are used to show the morphology of the wood samples and the distribution of DOT on their surface. ICP-OES results show that the average DOT concentration in the wood samples is originally 0.8 and 1.5 wt% in the bulk and at the surface, respectively. Conditioning of the wood to a moisture content of 19% in a climatic chamber reduces DOT concentration by 8% for the fir and 17% for the spruce. After one week of contact with the clays, the results showed a rapid decrease of 25-40% in DOT concentration in wood. On longer periods (5 months), the spruce shows a tendency to reabsorb the DOT from the clay and the DOT migration stabilizes at 20%. These results contribute to defining the dosage of DOT when the wood is exposed to clay.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Methods · Consensus signal: none
Teacher disagreement score0.640
Threshold uncertainty score0.464

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.052
GPT teacher head0.315
Teacher spread0.263 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it