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Record W4401711506 · doi:10.1016/j.cej.2024.154920

Advanced cold plasma-assisted technology for green and sustainable ammonia synthesis

2024· article· en· W4401711506 on OpenAlexafffund
Deepak Panchal, Qiuyun Lu, Ken Sakaushi, Xuehua Zhang

Bibliographic record

VenueChemical Engineering Journal · 2024
Typearticle
Languageen
FieldChemical Engineering
TopicAmmonia Synthesis and Nitrogen Reduction
Canadian institutionsUniversity of Alberta
FundersAlberta InnovatesNatural Sciences and Engineering Research Council of CanadaCanada Research Chairs
KeywordsAmmoniaPlasmaAmmonia productionEnvironmental scienceChemistryProcess engineeringNanotechnologyMaterials scienceEngineeringPhysicsOrganic chemistry

Abstract

fetched live from OpenAlex

Ammonia (NH 3 ) is the most crucial industrial chemical feedstock for producing fertilizers and is a promising future hydrogen carrier. Recent research has spurred for the development of alternative green and sustainable ammonia production technologies. Cold plasma technology provides a clean, sustainable method for nitrogen (N 2 ) conversion into active species for ammonia synthesis. Synergistic action of cold plasma and catalyst has significantly improved the current production rate and selectivity. Present energy consumption (2.1 MJ mol N −1 ) for N 2 fixation via plasma-assisted technology is still higher than the commercial process (0.7 MJ mol N −1 ), while a further improvement would be game-changing. In this review, we explain the takeover by plasma-assisted technology and its potential for green and sustainable ammonia production. We briefly present that the major challenge in nitrogen fixation of N 2 to NO x as an intermediate pathway, can be addressed by plasma technology via NO x transformation into targeted NH 3 product. We discussed the emerging plasma and catalysis synergism, mechanisms involved and highlighted current research development in selective ammonia generation. Finally, we outlined the ways to achieve cleaner and sustainable ammonia production and challenges in future work. • Cold plasma technology enables clean and sustainable approach to ammonia synthesis. • Synergy of plasma technology and catalytic reactions realized nitrogen fixation. • Energy-efficient and selective NH 3 synthesis require interdisciplinary research. • Advanced cold plasma technology may provide green NH 3 supply with net-zero economy.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.102
Threshold uncertainty score0.926

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.006
GPT teacher head0.209
Teacher spread0.203 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations37
Published2024
Admission routes2
Has abstractyes

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