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Development and experimental investigation of a new direct urea fuel cell

2024· article· en· W4402801749 on OpenAlexaff
Ayse Sinem Meke, İbrahim Dinçer

Bibliographic record

VenueInternational Journal of Hydrogen Energy · 2024
Typearticle
Languageen
FieldEngineering
TopicFuel Cells and Related Materials
Canadian institutionsOntario Tech University
Fundersnot available
KeywordsFuel cellsUreaChemistryNuclear engineeringChemical engineeringComputer scienceEngineeringOrganic chemistry

Abstract

fetched live from OpenAlex

This study concerns the development and experimental investigation of Direct Urea-Hydrogen Peroxide Fuel Cells (DUHPFC), with a particular emphasis on electrode preparation using nickel zinc iron oxide coated on stainless steel foil via the electrochemical deposition method, and the performance evaluation of single cells under varying operational conditions is also performed. This electrochemical deposition helps achieve a uniform and stable anode coating, which exhibits the high catalytic activity and stability, resulted in significantly enhanced urea oxidation reaction. The research further identifies an optimal performance for a single cell at 25 °C with 9 M KOH and 0.5 M urea, achieving a peak power density of 46.38 mW/cm 2 . The single cell demonstrates an open circuit voltage (OCV) of 0.72 V. Both energy and exergy efficiencies are further investigated for the cell performance and found to be 58% and 24%, respectively, at 5 M KOH. The electrochemical impedance spectroscopy (EIS) results reveal a significant reduction in impedance, from 30-Ωcm 2 at 25 °C to 15-Ωcm 2 at 65 °C, indicating an enhanced ionic conductivity and a reduced resistance. The present study results suggest that optimizing the electrode composition and operational parameters significantly improves the DUHPFC's performance, offering valuable insights for future fuel cell development. • Urea and H₂O₂ enhance electrochemical reactions in DUHPFC systems. • Nickel zinc iron oxide catalyst boosts urea oxidation and cell efficiency. • Optimizing electrode composition and conditions improves DUHPFC performance. • Temperature and KOH concentration affect urea oxidation and cell efficiency. • Testing confirms the stability and durability of the developed anode.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.003

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0010.001
Open science0.0010.001
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.009
GPT teacher head0.212
Teacher spread0.203 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations13
Published2024
Admission routes1
Has abstractyes

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