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Record W4403461938 · doi:10.1021/acs.inorgchem.4c02398

Higher-Magnesium-Doping Effects on the Singlet Ground State of the Shastry–Sutherland SrCu<sub>2</sub>(BO<sub>3</sub>)<sub>2</sub>

2024· article· en· W4403461938 on OpenAlexafffund
Lia Šibav, Žiga Gosar, Tilen Knaflič, Zvonko Jagličić, Graham King, Hiroyuki Nojiri, Denis Arčon, Mirela Dragomir

Bibliographic record

VenueInorganic Chemistry · 2024
Typearticle
Languageen
FieldPhysics and Astronomy
TopicAdvanced Condensed Matter Physics
Canadian institutionsCanadian Light Source (Canada)
FundersDivision of Materials ResearchInstitute for Materials Research, Tohoku UniversityCanadian Institutes of Health ResearchNatural Sciences and Engineering Research Council of CanadaEuropean CommissionH2020 Marie Skłodowska-Curie ActionsJavna Agencija za Raziskovalno Dejavnost RSInstitut "Jožef Stefan"Canadian Light Source
KeywordsChemistryMagnesiumDopingGround stateSinglet stateCondensed matter physicsAtomic physicsPhysicsExcited state

Abstract

fetched live from OpenAlex

High Resolution Image Download MS PowerPoint Slide Doping of quantum antiferromagnets is an established approach to investigate the robustness of their ground state against the competing phases. Predictions of doping effects on the ground state of the Shastry–Sutherland dimer model are here verified experimentally on Mg-doped SrCu 2 (BO 3 ) 2 . A partial incorporation of Mg 2+ on the Cu 2+ site in the SrCu 2 (BO 3 ) 2 structure leads to a subtle but systematic lattice expansion with the increasing Mg-doping concentration, which is accompanied by a slight decrease in the spin gap, the Curie–Weiss temperature, and the peak temperature of the susceptibility. These findings indicate a doping-induced breaking of Cu 2+ spin-1/2 dimers that is also corroborated by X-band EPR spectroscopy that points to a systematic increase in the intensity of free Cu 2+ sites with increasing Mg-doping concentration. Extending the Mg-doping up to nominal x = 0.10 yielding SrCu 1.9 Mg 0.1 (BO 3 ) 2, in the magnetization measurements taken up to 35 T, a suppression of the pseudo-1/8 plateau is found along with a clear presence of an anomaly at an onset critical field μ 0 H’ C0 ≈ 9 T. The latter, absent in pure SrCu 2 (BO 3 ) 2, emerges due to the pairwise coupling of liberated Cu 2+ spin-1/2 entities in the vicinity of Mg-doping induced impurities.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.018
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.006
GPT teacher head0.198
Teacher spread0.193 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations1
Published2024
Admission routes2
Has abstractyes

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