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Record W4404039562 · doi:10.3390/ma17215389

Adsorption of Lufenuron 50-EC Pesticide from Aqueous Solution Using Oil Palm Shell-Derived Activated Carbon

2024· article· en· W4404039562 on OpenAlexaff
David Alejandro Jeison Nuñez, Juan Barraza, Juan Guerrero-Pérez, Luis Carlos Díaz-Muegue, Ajay K. Dalai, Venu Babu Borugadda

Bibliographic record

VenueMaterials · 2024
Typearticle
Languageen
FieldEnvironmental Science
TopicWater Quality Monitoring and Analysis
Canadian institutionsUniversity of Saskatchewan
Fundersnot available
KeywordsActivated carbonAdsorptionLufenuronAqueous solutionPalm oilShell (structure)PesticideChemistryCarbon fibersEnvironmental chemistryChemical engineeringOrganic chemistryMaterials scienceComposite materialAgronomyBiologyFood scienceComposite number

Abstract

fetched live from OpenAlex

The use of Lufenuron 50-EC pesticide in oil palm crops affects water quality and aquatic life. This study investigated the adsorption of Lufenuron 50-EC from an aqueous solution using activated carbon derived from oil palm shells (OPSs). Activated carbon (AC) was prepared through physical and chemical activation processes in carbon dioxide environments, using potassium hydroxide (KOH) as a chemical activating agent. The resulting AC was characterized using standard techniques. The most favorable operating parameters were physical activation at 900 °C for 2 h, achieving a BET surface area of 548 m2/g. For chemical activation, at 800 °C, 1 h, and an impregnation ratio (KOH/biochar) of 2:1 (w/w), a BET surface area of 90 m2/g was obtained, which was smaller than that achieved by physical activation. The use of KOH reduced the surface area but generated a high presence of functional groups on the AC surface, which is important for adsorption processes. The AC produced achieved high Lufenuron adsorption yields, reaching a maximum of 96.93%. AC produced at 900 °C with 2 h showed the best performance. Therefore, OPS is an excellent precursor for producing AC with favorable characteristics for pollutant adsorption in aqueous solutions, especially for the insecticide Lufenuron.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.025
Threshold uncertainty score0.982

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.027
GPT teacher head0.257
Teacher spread0.230 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations2
Published2024
Admission routes1
Has abstractyes

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