Recent Advances in NIR‐Switchable Multi‐Redox Systems Based on Organic Molecules
Bibliographic record
Abstract
Electrochromic systems capable of switching absorption in the near-infrared (NIR) region (750-2500 nm) are attractive from the viewpoint of applications for material and life science, and thus several examples have been reported to date. In general, the development of organic-based systems is needed to reduce the environmental impact and improve biocompatibility. Although extending the switchable spectral range is crucial for the application of organic electrochromic molecules, the switching of NIR absorption based on redox interconversion is still a challenging issue regarding reversibility and durability during interconversion. To overcome this potential instability, the introduction of heteroatoms into the molecular backbone and/or π-extension could be useful strategies in terms of effective delocalization of charge and spin in the corresponding redox states. In this review, we focus on redox-active well-defined small molecules that enable ON/OFF switching of NIR absorption based on precise control of the redox states, and present recent studies on their intrinsic electrochemical and spectroscopic properties and/or structural characterization of their charged states.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.001 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.000 | 0.001 |
| Insufficient payload (model declined to judge) | 0.001 | 0.001 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".