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Record W4404126527 · doi:10.3749/2400023

Ehrigite, Bi8Te3, a New Member of the Tetradymite Group

2024· article· en· W4404126527 on OpenAlexaboutno aff
Cristiana L. Ciobanu, Nigel J. Cook, Jie Yao, Ashley D. Slattery, Benjamin P. Wade, Gabriel I. Dima

Bibliographic record

VenueThe Canadian Journal of Mineralogy and Petrology · 2024
Typearticle
Languageen
FieldMaterials Science
TopicCrystal Structures and Properties
Canadian institutionsnot available
Fundersnot available
KeywordsGroup (periodic table)Chemistry

Abstract

fetched live from OpenAlex

Abstract Ehrigite, Bi8Te3, is a new member of the tetradymite group and crystallizes in the trigonal crystal system (space group: , #166). Its cell dimensions are a = 4.519(6) Å, c = 65.182(24) Å, Z = 3, and V = 1152.771(7.554) Å3. Ehrigite occurs as sub-100-micron-sized grains in hedenbergite skarn from the abandoned Good Hope gold mine, Hedley district, British Columbia, Canada. The mineral and name have been approved by the IMA Commission on New Minerals and Mineral Nomenclature (proposal 2023-074). Ehrigite is compositionally and structurally distinct from hedleyite, Bi7Te3, with which it coexists. Ehrigite is opaque, with a pale gray color in reflected light. Reflectance is higher than tetradymite and slightly higher than hedleyite. It appears gray against native bismuth. The ehrigite structure consists of a single 11-atom layer visualized in atomic-scale high-angle annular dark field scanning transmission electron microscope images and further constrained from ab initio total energy calculations and structure relaxation using density functional theory using the measured parameters as input data. Scanning transmission electron microscope simulations also closely match the crystal structure model and images. Phases of the tetradymite and related modular mineral groups are well suited to visualization, indexing, and diffraction using a high-angle annular dark field scanning transmission electron microscope. The addition of density functional theory methodology to corroborate and refine structural characteristics provides a valuable approach for understanding these complex yet predictable minerals.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.709
Threshold uncertainty score0.987

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.015
GPT teacher head0.212
Teacher spread0.198 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designNot applicable
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations1
Published2024
Admission routes1
Has abstractyes

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Same venueThe Canadian Journal of Mineralogy and PetrologySame topicCrystal Structures and PropertiesFrench-language works237,207