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Record W4404391103 · doi:10.1080/15435075.2024.2427301

Life cycle assessment of biodiesel production using a nonionic surfactant and CaO from eggshell as a catalyst

2024· article· en· W4404391103 on OpenAlexaff
Maria Rosiane de Almeida Andrade, Jessyca Kaenny de Andrade Bezerra, Andréa Oliveira Nunes, Eduardo Lins de Barros Neto, Lindemberg de Jesus Nogueira Duarte, Jean‐Michel Lavoie

Bibliographic record

VenueInternational Journal of Green Energy · 2024
Typearticle
Languageen
FieldEngineering
TopicBiodiesel Production and Applications
Canadian institutionsUniversité de Sherbrooke
Fundersnot available
KeywordsBiodieselTransesterificationBiodiesel productionLife-cycle assessmentPulmonary surfactantPulp and paper industrySoybean oilMethanolWaste managementEnvironmental scienceEggshellChemistryCatalysisChemical engineeringMaterials scienceEngineeringOrganic chemistryProduction (economics)Food science

Abstract

fetched live from OpenAlex

Life cycle assessment (LCA) is a tool used to evaluate the environmental impacts and resources used to manufacture a product. The present study proposes an innovative and unprecedented based on LCA of biodiesel production from the methyl transesterification of soybean oil catalyzed by eggshell-derived CaO and using the nonionic surfactant nonylphenol ethoxylate (NP6EO). Biodiesel was produced under mild conditions with a 1:4 methanol-to-oil ratio, 2 wt% CaO, 1 wt% NP6EO, and reaction times of 2 hours with surfactant and 3 hours without, with a yield of 95.18% and 97.75%, respectively. The life cycle impact assessment (LCIA) was performed using the SimaPro software and the Ecoinvent 3.6 database by implementing the CML-IA baseline method. Results indicated that the catalyst preparation process had the lowest environmental impact, while soybean oil used contributed the most across all impact categories. The surfactant-based process was 77% more eco-efficient than the non-surfactant process. Results also showed that surfactant concentration has more influence on impacts than additional electricity consumption due to a longer reaction time. Compared to traditional KOH-catalyzed biodiesel production, the use of CaO from eggshells and NP6EO demonstrated a lower environmental impact, suggesting this method is a promising alternative to conventional processes.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.003
Threshold uncertainty score0.006

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0000.001
Bibliometrics0.0010.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.014
GPT teacher head0.277
Teacher spread0.263 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations3
Published2024
Admission routes1
Has abstractyes

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