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Record W4404718985 · doi:10.1080/15275922.2024.2431333

Identification of dominant natural sources of polycyclic aromatic hydrocarbons in river sediments in Alberta

2024· article· en· W4404718985 on OpenAlexaffabout
Philip I. Richards, Ifeoluwa Idowu, Gregg T. Tomy, Courtney D. Sandau

Bibliographic record

VenueEnvironmental Forensics · 2024
Typearticle
Languageen
FieldEnvironmental Science
TopicToxic Organic Pollutants Impact
Canadian institutionsUniversity of ManitobaCanmore Museum and Geoscience Centre
Fundersnot available
KeywordsEnvironmental chemistryNatural (archaeology)Identification (biology)Environmental scienceEarth scienceGeologyChemistryEcologyBiologyPaleontology

Abstract

fetched live from OpenAlex

Sediment collected from the rivers of southern Alberta, Canada, presents patterns of polycyclic aromatic hydrocarbons (PAHs) that demonstrate a varied origin within the Rocky Mountains. An influx of PAHs from sub-bituminous coal sources from erosional processes as the river exit the mountains dominates the pattern of PAHs in the river sediment across the prairies to the Alberta-Saskatchewan border (a distance of 750 km for the Red Deer River and 925 km for the Bow River) continues much further downstream. The concentrations of PAHs are similar to the well-studied Athabasca River in the Alberta Oil Sands Region. Although these results relate to rivers flowing east from the Rocky Mountains in Canada, it is likely that coal-sourced PAHs will contribute to any river where erosion of coal formations is possible within the watershed. A distinctive natural pattern of strongly pyrogenic PAHs from nearby thermal hot springs was also discovered near Banff. Natural pyrogenic PAH sources, aside from wildfires, are uncommon and generally related to hydrothermal vents and igneous intrusions into source rocks. This is the first time the authors are aware of sediment from a thermal spring presenting such PAH patterns.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.089
Threshold uncertainty score0.180

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0020.003
Science and technology studies0.0020.001
Scholarly communication0.0010.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.004
GPT teacher head0.209
Teacher spread0.205 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations1
Published2024
Admission routes2
Has abstractyes

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