Subnanometric Pt–W Bimetallic Clusters for Efficient Alkaline Hydrogen Evolution Electrocatalysis
Why this work is in the frame
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Bibliographic record
Abstract
Rational design and synthesis of subnanometric bimetallic clusters (SBCs) within a narrow size distribution, along with achieving full SBCs exposure on supporting materials, are formidable challenges that must be overcome to realize potential applications. This work details a facile strategy to synthesize fully exposed PtW SBCs with an average size of 0.81 nm on the surface of spherical N-doped carbon (PtW/NC), which is underpinned by the electrostatic interactions between the negatively charged [H 3 PtW 6 O 24 ] 5– polyanions and the positively charged closed-pore metal–organic framework (MOF) [Zn 5 (OH) 2 (AmTRZ) 6 ] 2+ . The PtW/NC exhibits significant electrocatalytic performance and stability for the alkaline hydrogen evolution reaction with an ultralow overpotential of 4 mV at 10 mA cm –2, a low Tafel slope of 29 mV dec –1, and a long-term electrolysis stability exceeding 140 h. The Pt mass activity of PtW/NC is 34 times higher than that of commercial 20 wt % Pt/C at the 100 mV overpotential. Both theoretical calculations and electrochemical measurements indicate that a synergistic effect between Pt and W is responsible for this notable catalytic performance. The synthetic approach outlined in this work can be applied to other MOFs and coordination networks that lack pores or have limited porosity.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.002 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.001 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it