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Record W4404867556 · doi:10.26434/chemrxiv-2024-1pm6z

Milling for Analytical Testing to Optimize Cannabinoid Recovery and Sample Throughput

2024· preprint· en· W4404867556 on OpenAlexaff
Sajni Shah, Eric Janusson, Markus Roggen

Bibliographic record

VenueChemRxiv · 2024
Typepreprint
Languageen
FieldPharmacology, Toxicology and Pharmaceutics
TopicForensic Toxicology and Drug Analysis
Canadian institutionsUniversity of British Columbia
Fundersnot available
KeywordsThroughputSample (material)CannabinoidComputer scienceReliability engineeringChromatographyEngineeringChemistryTelecommunications

Abstract

fetched live from OpenAlex

• Background In the cannabis industry, achieving accurate analytical test results is complex, hindered by challenges such as sampling issues, sample preparation, cross-contamination, and the choice of analytical methods. The heterogeneity of cannabis complicates obtaining representative samples, crucial for precise outcomes. Sample preparation is affected by the cannabis matrix's complexity, demanding specialized techniques for consistent analyte recovery. Cross-contamination during handling and the selection of analytical techniques like HPLC and GC also impact result accuracy. Furthermore, 'lab shopping' for favorable THC reports adds to the challenge, distorting product profiles and posing public health risks. • Objective This study investigates the impact of different milling instruments and conditions on cannabinoid recovery and sample throughput in analytical testing, and explores potential optimizations for cost, throughput, and contamination reduction, addressing gaps in current understanding. • Methods Samples of cannabis flower were milled according to various parameters and different mill types; an electric bladed mill and a food processor, with either reusable or single-use containers. • Results Investigations into milling methods for cannabis reveal that decarboxylation ratios or oxidation of THCA and CBDA flower do not significantly vary across different milling instruments or protocols. Single-use containers demonstrated improved cannabinoid recoveries, with specific conditions optimizing for THCA and THC or CBDA and CBD levels. • Conclusion This study delves into the impact of milling methods and operational parameters on cannabinoid analysis in cannabis, revealing that methodological choices significantly affect cannabinoid preservation. Notably, single-use containers at specific settings were optimal for maximizing THCA and THC levels, highlighting the importance of mill type and speed. However, the study also considers the operational and financial challenges of milling, suggesting that single-use containers may offer a balance between efficiency, sustainability, and cost-effectiveness. Furthermore, optimizing milling for THC preservation is economically advantageous, aligning operational efficiency with market demands. • Highlights The nuanced impact of milling conditions on cannabinoid preservation and extraction is highlighted.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.004
metaresearch head score (Gemma)0.006
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Methods · Consensus signal: Methods
Teacher disagreement score0.011
Threshold uncertainty score0.037

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0040.006
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0010.001
Science and technology studies0.0010.001
Scholarly communication0.0020.001
Open science0.0010.001
Research integrity0.0010.002
Insufficient payload (model declined to judge)0.0110.005

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.160
GPT teacher head0.434
Teacher spread0.274 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreMethods

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2024
Admission routes1
Has abstractyes

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