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Record W4405035945 · doi:10.1016/j.trac.2024.118097

Marine specialized metabolites: Unveiling Nature's chemical treasures from the deep blue

2024· article· en· W4405035945 on OpenAlexafffund
Thilina U. Jayawardena, Natacha Mérindol, Nuwan Sameera Liyanage, Fatima Awwad, Isabel Desgagné‐Penix

Bibliographic record

VenueTrAC Trends in Analytical Chemistry · 2024
Typearticle
Languageen
FieldBiochemistry, Genetics and Molecular Biology
TopicMarine Sponges and Natural Products
Canadian institutionsUniversité du Québec à Trois-Rivières
FundersUniversité du Québec à Trois-Rivières
KeywordsAstrobiologyChemistryBiology

Abstract

fetched live from OpenAlex

Marine specialized metabolites (MSM) represent a fascinating realm of chemical diversity with multifaceted functions across the spectrum of life on Earth. These metabolites serve as weapons, metal transporters, regulatory agents, and more. The conservation of genes responsible for their production over extensive evolutionary timescales underscores their selective advantage. Recent decades have witnessed an upsurge in MSM studies, driven by advancements in analytical techniques and the ever-growing accessibility of the aquatic environment. Marine macro and microorganisms offer a rich tapestry of specialized metabolites, some exhibiting potent activities in diverse domains, including medicine. The study of MSM presents several challenges, reflecting the need to separate complex mixtures into individual bioactive metabolites and utilize state-of-the-art extraction methods. Comprehensive structural analysis relies on advanced spectroscopic approaches, including nuclear magnetic resonance and mass spectrometry. These tools are instrumental in unravelling the chemical diversity of MSM and understanding their potential applications. While bioprospecting offers enormous potential, it raises critical challenges concerning sustainability, conservation, and equitable benefit-sharing. International protocols like the Nagoya Protocol seeks to regulate access to and share benefits from genetic resources, with considerable implications for marine bioprospecting. The convergence of advanced metabolomics, metagenomics, and synthetic biology offers promising avenues for accelerating the discovery and sustainable production of MSM, shaping the future of this field. This comprehensive review provides a deep dive into the challenges, methodologies, and emerging trends in studying marine-derived natural products, underscoring the immense potential of MSM for advancing chemical sciences and their transformative applications in diverse areas such as food, medicine, biotechnology, and environmental conservation. By bridging multiple disciplines, the continued exploration and sustainable utilization of these metabolites hold the promise of unlocking new innovations for society's benefit. • Marine specialized metabolites (MSM) offer multifaceted functions across life. • Advancements in analytical techniques have fueled a surge in MSM studies. • Structural analysis relies on advanced spectroscopic methods like NMR and MS. • Bioprospecting holds potential but raises sustainability & benefit-sharing concerns • Omics and synthetic biology promise accelerated discovery and production of MSM.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.219
Threshold uncertainty score0.999

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.011
GPT teacher head0.285
Teacher spread0.274 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations15
Published2024
Admission routes2
Has abstractyes

Explore more

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