Manganese Cycling Driven by Fluctuating Redox Chemocline in the Ediacaran Ocean
Bibliographic record
Abstract
Abstract The Ediacaran Period, immediately following the Neoproterozoic Cryogenian glaciations, marked a crucial phase in the Earth's evolutionary history. The paleo‐oceanic environment helped shape the habitability, yet the links between oceanic redox state, hydrochemistry, biological activity, and elemental cycling during this time remain poorly understood. Here, we address this scientific issue based on high‐resolution geochemical data from black shale‐hosted, manganese (Mn)‐rich carbonates within the upper Ediacaran Doushantuo Formation, located on the northern margin of the Yangtze Block, South China. Multiple redox proxies indicate that while the open ocean may have been intermittently oxygenated during the late Ediacaran glaciation, the continental margin slope was characterized by redox stratified conditions with a fluctuating redox interface. These fluctuations were driven by climatic shifts. During the deposition of black shales, a relatively warm and humid climate caused a notable increase in freshwater runoff and glacial meltwater, raising water levels and lowering salinity. The influx of bioessential elements carried by terrestrial runoff promoted primary productivity. By contrast, the deposition of the Mn(II) carbonates occurred under colder, more arid conditions, with limited terrigenous nutrient input, leading to lower organic carbon production. This resulted in the deepening of the redox chemocline over the continental shelf, promoting Mn(II) oxidation and subsequent mineralization. Paleoclimate‐driven redox fluctuations were key in controlling elemental cycling during the late Ediacaran. This may offer insights into similar processes throughout Earth's history.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.003 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.001 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.000 | 0.001 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".