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Record W4405188106 · doi:10.3390/batteries10120436

Beyond Organic Electrolytes: An Analysis of Ionic Liquids for Advanced Lithium Rechargeable Batteries

2024· article· en· W4405188106 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueBatteries · 2024
Typearticle
Languageen
FieldEngineering
TopicAdvanced Battery Materials and Technologies
Canadian institutionsConcordia University
FundersConcordia University
KeywordsElectrolyteFlammabilityIonic conductivityThermal runawayMaterials scienceBattery (electricity)Ionic liquidOrganic radical batterySupercapacitorEnergy storageElectrochemistryComputer scienceNanotechnologyProcess engineeringElectrodeChemistryEngineeringComposite materialOrganic chemistry

Abstract

fetched live from OpenAlex

The fast-growing area of battery technology requires the availability of highly stable, energy-efficient batteries for everyday applications. This, in turn, calls for research into new battery materials, especially with regard to a battery’s main component: the electrolytes. Besides the demands associated with solid ionic conduction and appropriate electrochemical behaviour, considerable effort will be necessary to thoroughly reduce safety risks in terms of flammability, leakage, and thermal runaway. Consequently, completely new classes of electrolytes need to be developed that are compatible with energy storage systems. Despite the progress made in solid polymer electrolytes, such materials have suffered from limitations to their real-world application. Now, ionic liquids are considered a class of electrolytes with the most potential for the creation of more advanced and safer lithium–ion batteries. In recent decades, ILs have been widely explored as potential electrolytes in the search for new breakthroughs in the ESS field, such those associated with fuel cells, lithium–ion batteries, and supercapacitors. The present review will discuss ILs that present high ionic conductivity, a lower melting point below 100 °C, and which feature up to 5–6 V wide electrochemical potential windows vs. Li+/Li. Furthermore, ILs exhibit good thermal stability, non-flammability, and low volatility—all of which are attributes realized by appropriate cation–anion combinations. This paper seeks to review the status of research concerning ILs, along with the advantages and challenges yet to be overcome in their development.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.043
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.001
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.008
GPT teacher head0.239
Teacher spread0.231 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it