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Record W4405519167 · doi:10.1021/acssuschemeng.4c07940

3D Printing of High Strength Thermally Stable Sustainable Lightweight Corrosion-Resistant Nanocomposite by Solvent Exchange Postprocessing

2024· article· en· W4405519167 on OpenAlexaff
Sayan Ganguly, Xiaowu Tang

Bibliographic record

VenueACS Sustainable Chemistry & Engineering · 2024
Typearticle
Languageen
FieldMaterials Science
TopicAdvanced Cellulose Research Studies
Canadian institutionsUniversity of Waterloo
Fundersnot available
KeywordsMaterials scienceThermogravimetric analysisNanocompositeThermal stabilityComposite materialCorrosionUltimate tensile strengthSolventCelluloseExtrusionChemical engineeringOrganic chemistryChemistry

Abstract

fetched live from OpenAlex

3D printing of cellulose acetate (CA)-based, sustainable, thermally stable nanocomposites is challenging due to their fast drying, nozzle clogging, and complex rheological behavior. In this study, we developed an extrusion-printable ink based on CA and cellulose nanocrystals (CNCs) using a trisolvent wet blending method, followed by a postprinting pore-inducing processing technique. The nanocomposites performed well in both tensile- and compression-based mechanical tests. Moreover, the nanocomposites demonstrated malleable deformation during compression testing without any premature fracture, unlike commercial commodity plastics. The thermal stability was assessed using thermogravimetric analysis, showing a ∼ 28 °C improvement in the onset degradation temperature after the addition of 5 wt % CNCs. Solvent tolerance tests against various solvents indicated excellent solvent resistance. The lightweight nanocomposites showed no deterioration, even after long-term exposure to water vapor. Finally, the anticorrosion behavior of the samples was evaluated as a coating material for metal (Al), demonstrating excellent protection against corrosive acid vapors. Thus, the application of 3D-printed CA material exhibits significant promise for implementation in the fields of lightweight, sustainable, and anticorrosive engineering materials.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.030
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.001
Open science0.0010.001
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.005
GPT teacher head0.222
Teacher spread0.218 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations26
Published2024
Admission routes1
Has abstractyes

Explore more

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