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Record W4405586020 · doi:10.1016/j.seppur.2024.131207

Capturing and converting CO2 using amino acids as various commercially valuable nano-carbonates

2024· article· en· W4405586020 on OpenAlexaff
Qingyang Li, Yongteng Qian, Malcolm Xing, Bingyun Li

Bibliographic record

VenueSeparation and Purification Technology · 2024
Typearticle
Languageen
FieldChemical Engineering
TopicCarbon dioxide utilization in catalysis
Canadian institutionsUniversity of Manitoba
FundersNational Institute for Occupational Safety and HealthCenters for Disease Control and PreventionWest Virginia UniversityWest Virginia Higher Education Policy CommissionNational Institute of Food and AgricultureNational Institutes of Health
KeywordsNano-Amino acidChemistryEngineeringChemical engineeringBiochemistry

Abstract

fetched live from OpenAlex

Carbon dioxide (CO 2 ) is the most significant greenhouse gas and one of the strategies to reduce CO 2 emission is to convert CO 2 into commercially valuable products. Currently, methods that can effectively capture and convert CO 2 into carbonate nanomaterials, which have unique applications in various fields, have rarely been reported, and there are no universal methods that can capture and convert CO 2 into different nano-carbonates. In this study, an innovative two-step strategy based on amino acids was developed to produce multiple different carbonate nanoparticles , including CaCO 3 , BaCO 3 , and Ag 2 CO 3 nanoparticles with diameters of 70 nm, 50 nm, and 7 nm, respectively. Fundamentally important, the nuclear magnetic resonance data clearly demonstrated that it was the amino acids (e.g., glycine) that dictated the formation of carbonate nanoparticles. In the presence of amino acids, a competition in forming nanoparticles and microparticles was observed, and the formation of nanoparticles was proportional to the carbamate formed from CO 2 reacting with amino acids. In the absence of amino acids, carbonate microparticles (∼ 2 µm) were formed.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.620
Threshold uncertainty score0.739

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.016
GPT teacher head0.283
Teacher spread0.267 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations8
Published2024
Admission routes1
Has abstractyes

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