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Achieving high performance and durability with ultra-low precious metal nanolayer on porous transport layer for PEMWE application

2024· article· en· W4405667020 on OpenAlex
Abhay Gupta, Yasin Mehdizadeh Chellehbari, Samaneh Shahgaldi

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueJournal of Power Sources · 2024
Typearticle
Languageen
FieldMaterials Science
TopicMXene and MAX Phase Materials
Canadian institutionsUniversité du Québec à Trois-Rivières
FundersNatural Sciences and Engineering Research Council of CanadaMitacsCanada Research Chairs
KeywordsDurabilityPorosityMaterials scienceLayer (electronics)Precious metalNanotechnologyMetallurgyMetalChemical engineeringComposite materialEngineering

Abstract

fetched live from OpenAlex

Green hydrogen produced from polymer electrolyte membrane water electrolysis (PEMWE) provides a promising pathway to decarbonization. However, excessive dependence on Pt and Ir in the catalyst synthesis and anticorrosive coating on porous transport layers (PTL) drives the cost of PEMWE technology . As an alternative to the Pt-coated commercial PTL, sputtered multilayer and co-deposited TaPt coatings with low Pt loading were developed. Ex-situ electrochemical and physical characterizations (potentiostatic and galvanostatic polarization, scanning electron microscopy, interfacial contact resistance (ICR) testing, and x-ray photoelectron spectroscopy), and in-situ PEMWE cell testing was conducted to examine the PTL coating viability. Under the ex-situ PTL electrochemical stability analysis protocol developed in this work, the multilayered TaPt coating exhibited a higher simulated durability (96 h at 2.0 A cm −2 ) and lower ICR (1.9 mΩ cm 2 ) than the existing commercial Pt-coated PTL (15 h simulated durability and 2.1 mΩ cm 2 ). Low compressive stress and low extent of Galvanic coupling led to an improvement in the durability, conductivity, and in-situ performance of the TaPt multilayered PTL coating.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.018
Threshold uncertainty score0.419

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.008
GPT teacher head0.235
Teacher spread0.227 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it