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Record W4405842104 · doi:10.1016/j.cscm.2024.e04167

Chloride threshold level determination: Call for test standardization to limit variations in experimental methodology and resolve inherent experimental and modelling detection challenges

2024· article· en· W4405842104 on OpenAlexafffund
Nicolas Maamary, Ibrahim G. Ogunsanya

Bibliographic record

VenueCase Studies in Construction Materials · 2024
Typearticle
Languageen
FieldChemical Engineering
TopicAnalytical Chemistry and Sensors
Canadian institutionsUniversity of Toronto
FundersCanada Foundation for Innovation
KeywordsStandardizationLimit (mathematics)Detection limitTest (biology)Computer scienceReliability engineeringStatisticsEngineeringMathematicsGeology

Abstract

fetched live from OpenAlex

Chloride-induced corrosion significantly threatens the durability of reinforced concrete structures, leading to deterioration, costly repairs, and potential structural failures. Accurately determining the steel reinforcing bar (rebar) chloride threshold level (CTL) is crucial for predicting corrosion onset, optimizing material selection, and estimating the service life of these structures. An ensemble machine learning model was trained using literature CTL data. Despite achieving a mean absolute error of 0.218 % weight of binder, a root mean square error of 0.321 % weight of binder, and an R² value of 0.751 on unseen data, the model's performance reveals limitations due to the wide variability in reported CTL, stemming from disparities in experimental methodologies including set-up and corrosion detection techniques. After model development, this paper also investigates challenges associated with CTL evaluation by comparing literature practices and providing insights to enhance data reliability and comparability. Factors impacting CTL evaluation includes corrosion detection techniques, initiation criteria, chloride introduction methods, testing setup, exposure solution compositions, chloride concentration measurement techniques, and rebar concrete/mortar cover thickness. This paper focused on the largely ignored aspect of these factors, some of which are inherent and nearly non-circumventable, and will continue to lead to suboptimal performance of any CTL predictive model when not addressed. Recommendations for standardizing practices are proposed to improve CTL assessment consistency, reliability of developed CTL predictive models, and accuracy of service life modeling. • The ensemble model achieved 0.218 % MAE and 0.321 % RMSE in CTL predictions. • CTL variability stems from inconsistent experimental methods across studies. • Standardized testing is proposed to improve CTL data reliability and consistency. • Emphasized need for uniform corrosion detection and chloride measurement. • Recommendations aim to enhance CTL model accuracy and service life predictions.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.114
Threshold uncertainty score0.619

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.225
GPT teacher head0.387
Teacher spread0.162 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations4
Published2024
Admission routes2
Has abstractyes

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