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Record W4406138302 · doi:10.1021/acsestwater.4c00762

Electrocoagulation Using a Hybrid Combination of Iron and Aluminum Electrodes with Asymmetric Polarity Reversal

2025· article· en· W4406138302 on OpenAlex
Mudasar Mahmood, Nael Yasri, Edward P.L. Roberts

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueACS ES&T Water · 2025
Typearticle
Languageen
FieldEnvironmental Science
TopicAdvanced oxidation water treatment
Canadian institutionsUniversity of Calgary
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsPolarity reversalElectrocoagulationAnodePassivationCathodeElectrodeMaterials scienceDissolutionAluminiumPolarity (international relations)Cathodic protectionVoltageChemical engineeringChemistryMetallurgyComposite materialLayer (electronics)Electrical engineering

Abstract

fetched live from OpenAlex

This study explores the use of asymmetric polarity reversal (PR) in continuous electrocoagulation (EC) for removing silica and hardness using Fe/Al hybrid electrodes. Asymmetric PR takes advantage of aluminum’s tendency to undergo cathodic dissolution by alternating a “forward” current with cheaper iron anodes and a shorter reverse current with aluminum as the anode, as iron cathodes are not prone to dissolution. Adjusting the polarity reversal time (PRT) varied the relative dosing of the Fe and Al coagulants. Silica removal exceeded 95% across all asymmetric PRTs at a fixed charge loading of 2000 C L –1, with energy consumption between 1.44 and 1.93 kWh m –3 . Symmetric 10 min PRT achieved 90% Ca and 75% Mg removal, outperforming direct current (DC) EC. Both asymmetric PRTs of 10 min (Fe) and 30 s (Al) and a symmetric PRT of 10 min (Fe/Al) achieved high contaminant removal and relatively low treatment costs while using different amounts of Fe and Al. These configurations also lowered the cell voltage due to reduced fouling and passivation. This hybrid EC with asymmetric PR offers a novel, cost-effective method for adjusting the performance and optimizing the cost of wastewater treatment.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.146
Threshold uncertainty score0.304

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.006
GPT teacher head0.224
Teacher spread0.218 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it