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Record W4407830689 · doi:10.1007/978-3-031-80892-0_4

Reductive Leaching Investigation of Li-NMC Cathode Material Related to Spent Battery Recycling

2025· book-chapter· en· W4407830689 on OpenAlexaff
Gökçe Kiliç, Krystal Davis, George P. Demopoulos

Bibliographic record

Venue˜The œminerals, metals & materials series · 2025
Typebook-chapter
Languageen
FieldEngineering
TopicExtraction and Separation Processes
Canadian institutionsNational Research Council CanadaMcGill University
Fundersnot available
KeywordsLeaching (pedology)CathodeBattery (electricity)Environmental scienceMaterials scienceMetallurgyWaste managementEngineeringElectrical engineeringPhysicsSoil science

Abstract

fetched live from OpenAlex

The electrification of transportation and proliferation of portable electronics are rapidly increasing, leading to a significant demand for Li-ionLithium-ion battery batteriesBattery (LIBs)LIB batteries, specifically NMCNMC-type batteriesBattery. This surge in demand for Li, Ni, Mn, and Co elements is unsustainable if it relied solely on mining. Therefore, the need to prioritize lithiumLithium-ionLithium-ion battery battery recyclingBattery recycling in the coming decades is not just important, but urgent. While the hydrometallurgyHydrometallurgy process is considered greener for metal recoveryMetal recovery compared to pyrometallurgy, it requires further enhancements to address sustainabilitySustainability and environmental issues. These include reducing excessive acid usage and concomitant waste minimization (acidic wastewater and Na2SO4 production). To address these issues, the present work focused on improving the leachingLeaching efficiency of spent NMCNMC cathode material using a minimum amount of acid. We carried out the reductive leachingReductive leaching of spent Li-NMCNMC in H2SO4 media in a redox-controlled single feed semi-batch reactor through the regulated addition of H2O2.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Insufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: none
Teacher disagreement score0.432
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.001
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.022
GPT teacher head0.250
Teacher spread0.228 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2025
Admission routes1
Has abstractyes

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