MétaCan
Menu
Back to cohort
Record W4407853091 · doi:10.1021/acsestwater.4c01054

Urbanization Impacts Dissolved Organic Matter Concentration and Quality in a Southeastern United States Watershed

2025· article· en· W4407853091 on OpenAlex
Gwendolyn M. Hopper, Erik M. Smith, Jade Dormoy-Boulanger, Claudia R. Benitez‐Nelson

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueACS ES&T Water · 2025
Typearticle
Languageen
FieldEarth and Planetary Sciences
TopicMarine and coastal ecosystems
Canadian institutionsUniversité du Québec à Trois-Rivières
FundersUniversity of South CarolinaOffice for Coastal ManagementNational Oceanic and Atmospheric AdministrationNational Science Foundation
KeywordsUrbanizationWatershedEnvironmental scienceOrganic matterDissolved organic carbonWater qualityWater resource managementHydrology (agriculture)Environmental chemistryGeologyChemistryEcologyEconomicsEconomic growthComputer science

Abstract

fetched live from OpenAlex

High Resolution Image Download MS PowerPoint Slide Blackwater rivers are named due to their exceptionally high concentrations of chromophoric dissolved organic matter (CDOM). They are the predominant lotic ecosystem in the United States Southeastern Coastal Plain, a region experiencing some of the nation’s highest rates of development. This study assessed variability in DOM concentration and composition across forested to urbanized blackwater systems in coastal South Carolina, U.S. Dissolved organic carbon and nutrient concentrations as well as absorbance and fluorescence optical properties reveal that urban sites have lower concentrations, elemental ratios, and less complex DOM. In contrast, forested blackwater sites have concentrations an order of magnitude higher, elevated elemental ratios, and molecular size dominated by refractory terrestrial-like DOM. Urban blackwater rivers were observed to have DOM concentrations and composition more similar to brown water systems than rural blackwater systems. These findings suggest that the urbanization of blackwater ecosystems results in lower concentrations and the export of simpler, more labile DOM, potentially lowering dissolved oxygen concentrations, increasing atmospheric carbon emissions and other negative impacts. To protect blackwater systems, baseline DOM concentrations and composition must be established to decipher impacts on water quality due to naturally occurring versus anthropogenic activities and to properly assign classifications to these diverse systems across the U.S.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.012
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.009
GPT teacher head0.209
Teacher spread0.200 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it