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Record W4408214757 · doi:10.1002/sia.7392

What's in a Name? “ESCA” or “XPS”? A Discussion of Comments Made by Kai Siegbahn More Than Four Decades Ago Regarding the Name of the Technique

2025· article· en· W4408214757 on OpenAlexaff
Joshua W. Pinder, Braxton Kulbacki, Donald R. Baer, Mark C. Biesinger, J. E. Castle, David G. Castner, Christopher D. Easton, John T. Grant, Grzegorz Greczyński, Sarah L. Harmer, A.E. Hughés, Mark A. Isaacs, L. Kövér, George H. Major, David Morgan, C. J. Powell, Peter M. A. Sherwood, William Skinner, Kara J. Stowers, Jeff Terry, Matthew R. Linford

Bibliographic record

VenueSurface and Interface Analysis · 2025
Typearticle
Languageen
FieldMaterials Science
TopicElectron and X-Ray Spectroscopy Techniques
Canadian institutionsWestern University
FundersEngineering and Physical Sciences Research Council
KeywordsX-ray photoelectron spectroscopyEngineeringChemical engineering

Abstract

fetched live from OpenAlex

ABSTRACT In an interview in 1982, which was 1 year after he shared the Nobel Prize, Kai Siegbahn was asked about his opinion regarding the name of the technique he had developed. Siegbahn had named it “electron spectroscopy for chemical analysis” (ESCA), but the community was choosing to call it “X‐ray photoelectron spectroscopy” (XPS). Now, more than 40 years later, 20 XPS experts have given their opinions on Siegbahn's response and the name of the technique. Some of these participants have been doing XPS for many years and have provided a historical perspective on this issue. While there is no call in these comments for the community to return to “ESCA”—“XPS” is regarded as a more than an adequate name, and insisting on a name change at this point in time would probably only create confusion. However, some of the participants of this study still consider “ESCA” to be an acceptable way to refer to the technique, especially when it is used in a chemical context.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.051
metaresearch head score (Gemma)0.085
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesScience and technology studies
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: Not applicable
GenreCandidate signal: Commentary · Consensus signal: Commentary
Teacher disagreement score0.988
Threshold uncertainty score0.267

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0510.085
Meta-epidemiology (narrow)0.0020.001
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0010.002
Science and technology studies0.0120.015
Scholarly communication0.0060.011
Open science0.0030.005
Research integrity0.0150.023
Insufficient payload (model declined to judge)0.0050.002

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.011
GPT teacher head0.309
Teacher spread0.298 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

Study designNot applicable
Domainnot available
GenreCommentary

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations4
Published2025
Admission routes1
Has abstractyes

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