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Record W4408428951 · doi:10.5194/egusphere-egu25-14616

Improving Black Carbon Emission Estimates at Global Scale Using GEOS-Chem model and 4D-Var assimilation of TROPOMI/GRASP data

2025· preprint· en· W4408428951 on OpenAlexaboutno aff
Abhinna Behera, Cheng Chen, Оleg Dubovik, Pavel Litvinov, Yixuan Gu, Daven K. Henze, Tatyana Lapyonok, F. Thieuleux, Benjamin Guinot

Bibliographic record

Venuenot available
Typepreprint
Languageen
FieldEnvironmental Science
TopicAtmospheric and Environmental Gas Dynamics
Canadian institutionsnot available
Fundersnot available
KeywordsData assimilationGRASPScale (ratio)Environmental scienceAtmospheric sciencesMeteorologyEconometricsClimatologyComputer scienceMathematicsGeographyPhysicsGeologyCartography

Abstract

fetched live from OpenAlex

Radiative forcing by light-absorbing aerosols, particularly black carbon (BC), a major climate forcing agent alongside CO2 and CH4, remains poorly constrained due to insufficient characterisation of their optical properties and highly variable spatio-temporal distributions. Here we aim to refine BC’s spatio-temporal variability using the GEOS-Chem 3D Eulerian chemistry-transport model, which incorporates BC’s well-defined physical and chemical properties. The model includes aerosol-phase chemistry relevant to urban atmospheres, such as desert dust, BC, organic carbon, sea salts, SiO2, metal oxides, SO4²⁻, NO3-, NH4⁺, Na⁺, and Ca²⁺, at a global resolution (2°×2.5°) with primary aerosols only. Our primary objective is to precisely map BC’s spatial and temporal distributions, which is critical for evaluating the long-term impact of absorbing aerosols on net radiative forcing.Using the 4D-Var assimilation method with TROPOMI/GRASP aerosol optical depth (AOD) and aerosol absorption optical depth (AAOD) data, we adjust global-scale emissions at an hourly resolution from March 2019 to November 2020. From a satellite remote sensing perspective, this characterization of aerosols via a single-viewing spectrometer is unprecedented. The GRASP open-source algorithm has generated this novel dataset. The GEOS-Chem model is driven by 3-hourly meteorological fields obtained from GEOS-FP reanalysis data. Our study includes the extreme events of the Australian bushfire season and Canadian forest fire events, where we identify emission sources absent from the GFED3 inventories (1996–2012) used in the forward run. Assimilation of TROPOMI/GRASP AOD and AAOD data into the model allows to reproduce carbonaceous aerosol emissions. These results are validated using MODIS and VIIRS RGB imagery. Ground-level BC concentrations are further validated against in situ measurements from France in the frame of the ANR BLACKNET project and from AERONET. This framework will enable creating a global particulate matter (PM) database with high temporal resolution, spanning several years. Satellite data alone cannot achieve this level of detail. High-resolution BC distribution via inverse modelling will benefit from future spaceborne multi-angular polarimetric sensors, such as 3MI, CO2M MAP, and PACE. Additionally, aerosol vertical distributions will be studied to assess their influence on temperature profiles and atmospheric stability. This work will aid in validating and comparing suborbital measurements. The inverse modelling approach aligns closely with LiDAR-based observations from the EarthCARE mission.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.002
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Simulation or modeling · Consensus signal: Simulation or modeling
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.075
Threshold uncertainty score0.150

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.002
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0010.001
Science and technology studies0.0000.000
Scholarly communication0.0010.001
Open science0.0010.001
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0020.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.021
GPT teacher head0.260
Teacher spread0.239 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designSimulation or modeling
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2025
Admission routes1
Has abstractyes

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