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Polyhydroxyalkanoates (PHA) production in a circular CO2 economy: it's role in mitigating global CO2 emissions

2025· article· en· W4409323134 on OpenAlexafffund
Zhiyuan Zong, Chitong Rao, C. M. Du, Rong Lü, D. Chester Upham

Bibliographic record

VenueResources Conservation and Recycling · 2025
Typearticle
Languageen
FieldMaterials Science
Topicbiodegradable polymer synthesis and properties
Canadian institutionsUniversity of British Columbia
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsPolyhydroxyalkanoatesCircular economyProduction (economics)Natural resource economicsEnvironmental scienceEconomicsWaste managementBusinessEngineeringMicroeconomicsEcologyBiology

Abstract

fetched live from OpenAlex

• A universal carbon footprint model demonstrates that PHA production results in negative emissions. • The cradle-to-grave carbon footprint of PHA derived from waste cooking oil can be reduced to half that of fossil-based plastics. • Compared to fossil-based plastics, PHA production shows lower impacts on resources, ecosystems and human health even when green electricity is not fully available. • With a carbon tax credit, PHA production would be 11 % more cost-effective than fossil-based plastics. • 83 % of CO 2 equivalent emissions from the plastic industry can be mitigated through the use of alternative PHA combined with advanced recycling technologies. The use of fossil-fuel derived plastic significantly contributes to resource depletion and global warming. This study provides a life cycle assessment of PHA production, including (1) fully transparent in-plant data with a cradle-to-grave scope, (2) a universal life cycle model with varying input variables to ensure results are adaptable to different scenarios, (3) optimization pathways for both environmental and economic aspects, and (4) forecasts of potential impacts and compare with recycled plastic across different future timelines and locations. The cradle-to-grave carbon footprint of PHA is determined to be 5.77 kg-CO 2 e/kg-PHA today - nearly equivalent to that of conventional fossil-based plastics (5.52 kg-CO 2 e/kg-plastic) – however, with reasonable improvements projected for 2030/35, PHA would result in a carbon footprint of 2.01 kg-CO 2 e/kg-PHA. The cost is also found to be similar ($1168/t vs $1320/t).

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.507
Threshold uncertainty score0.467

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.017
GPT teacher head0.243
Teacher spread0.226 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations17
Published2025
Admission routes2
Has abstractyes

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