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Record W4410541520 · doi:10.1007/s43832-025-00228-8

Biosurfactant-producing bacteria counteract hydrocarbon-driven delay of sulfolane migration in groundwater

2025· article· en· W4410541520 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueDiscover Water · 2025
Typearticle
Languageen
FieldEnvironmental Science
TopicMicrobial bioremediation and biosurfactants
Canadian institutionsUniversity of Guelph
FundersNatural Sciences and Engineering Research Council of CanadaShell Canada
KeywordsSulfolaneGroundwaterBacteriaHydrocarbonChemistryEnvironmental sciencePetroleum engineeringGeologyGeotechnical engineeringOrganic chemistryPaleontology

Abstract

fetched live from OpenAlex

Sulfolane is a worldwide water-soluble pollutant, which typically migrates rapidly in impacted aquifers, with risks to water bodies and drinking water wells. Sulfolane migration may be delayed in sites co-polluted by hydrocarbons, which move more slowly and in which sulfolane partitions. However, when bacteria such as Pseudomonas aeruginosa aerobically biodegrade hydrocarbons and sulfolane, they generate biosurfactants (such as rhamnolipids). These enclose sulfolane within micelles and droplets, as seen by optical microscopy, and hamper its partitioning into hydrocarbons, as shown by Fourier transform infrared spectroscopy. Therefore, biosurfactants have the potential to accelerate sulfolane migration in groundwater, compared to scenarios where biosurfactant-producing bacteria are absent. These findings will aid safe management of impacted sites, where aerobic bacterial bioremediation is used for pollutant clean-up. When aerobic bacterial activity is promoted to enable pollutant biodegradation, sulfolane migration may accelerate before clean-up is complete, begging for careful monitoring of pollutant plumes.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.020
Threshold uncertainty score0.999

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.006
GPT teacher head0.213
Teacher spread0.207 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it