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Record W4410566441 · doi:10.5194/acp-25-5199-2025

Quantifying the sources of increasing stratospheric water vapour concentrations

2025· article· en· W4410566441 on OpenAlexafffund
Patrick E. Sheese, Kaley A. Walker, C. D. Boone, David A. Plummer

Bibliographic record

VenueAtmospheric chemistry and physics · 2025
Typearticle
Languageen
FieldEarth and Planetary Sciences
TopicAtmospheric Ozone and Climate
Canadian institutionsEnvironment and Climate Change CanadaUniversity of WaterlooUniversity of Toronto
FundersCanadian Space Agency
KeywordsEnvironmental scienceAtmospheric sciencesWater vaporEnvironmental chemistryClimatologyMeteorologyChemistryGeologyPhysics

Abstract

fetched live from OpenAlex

According to satellite measurements from multiple instruments, water vapour (H 2 O) concentrations, in most regions of the stratosphere, have been increasing at a statistically significant rate of ∼1 %–5 % per decade since the early 2000s. Previous studies have estimated stratospheric H 2 O trends, but none have simultaneously quantified the contributions from all main sources (temperature variations in the tropical tropopause region, changes in the Brewer–Dobson circulation, and changes in methane (CH 4 ) concentrations and oxidation) at all latitudes. Atmospheric Chemistry Experiment–Fourier Transform Spectrometer (ACE-FTS) measurements are used to estimate altitude-/latitude-dependent stratospheric H 2 O trends from 2004–2021 due to these sources. Results indicate that rising temperatures in the tropical tropopause region play a significant role in the increases, accounting for ∼1 %–4 % per decade in the tropical lower mid-stratosphere and in the mid-latitudes below ∼20 km. By regressing to ACE-FTS N 2 O concentrations, it is found that, in the lower mid-stratosphere, general circulation changes have led to both significant H 2 O increases and significant H 2 O decreases on the order of 1 %–2 % per decade depending on the altitude/latitude region. Making use of measured and modelled CH 4 concentrations, the increase in H 2 O due to CH 4 oxidation is calculated to be ∼1 %–2 % per decade above ∼30 km in the Northern Hemisphere and throughout the stratosphere in the Southern Hemisphere. After accounting for these sources, there are still regions of the mid-latitude lower mid-stratosphere that exhibit significant residual H 2 O trends increasing at 1 %–2 % per decade. Results indicate that these unaccounted-for increases could potentially be explained by increases in upper-tropospheric molecular hydrogen.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.017
Threshold uncertainty score0.034

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0010.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.012
GPT teacher head0.223
Teacher spread0.211 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2025
Admission routes2
Has abstractyes

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