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Record W4411075188 · doi:10.1029/2025jc022450

Oxygen Minimum‐Zone Expansion Controls Critical Metal Enrichment and Growth Rates in a Ferromanganese Crust From the Central Pacific Ocean

2025· article· en· W4411075188 on OpenAlexaff
Jieqi Xing, Yinan Deng, Jiangbo Ren, James R. Hein, Haiyang Xian, Long Li, Xiaodong Jiang, Yiping Yang, Gaowen He, Haijun Qiu, Jianxi Zhu

Bibliographic record

VenueJournal of Geophysical Research Oceans · 2025
Typearticle
Languageen
FieldEarth and Planetary Sciences
TopicGeochemistry and Elemental Analysis
Canadian institutionsUniversity of Alberta
FundersShenzhen Graduate School, Peking University
KeywordsFerromanganeseGeologyOxygen minimum zoneCrustOxygenOceanic crustOceanographyGeochemistryEarth scienceManganeseMetallurgyChemistryMaterials sciencePaleontologySubductionTectonics

Abstract

fetched live from OpenAlex

Abstract Hydrogenetic ferromanganese crusts (FMCs) rich in critical metals [for example, cobalt (Co), nickel (Ni), and rare‐earth elements plus yttrium (REY)] are known as promising mineral resources for the transition to a net‐zero carbon emission future. The oxygen minimum zone (OMZ) has an important influence on the formation of FMCs, but its controlling mechanism for the enrichment of critical metals in FMCs is poorly constrained, hindering a fuller understanding of and exploration for critical metal‐rich FMCs. The studied FMC (∼2,000 m depth) collected just below the oxygen minimum zone (OMZ; ∼300–1,000 m depth) in the central Pacific Ocean records the OMZ expansion during FMC formation; key evidence of this is changes in the size of the positive Ce anomaly and positive shifts in δ 15 N values. Our data indicate that OMZ expansion reduces FMCs growth rates over time, with texture transitions from dendritic to botryoidal. The OMZ expansion contributes to an increase in Mn oxides with Co and Ni enrichment and a decrease in the Fe oxyhydroxides and REY content. Our findings underscore the pivotal role of global OMZ expansion in influencing the growth dynamics of FMCs and the accumulation of critical metals, which is crucial for understanding the enrichment and cycling of critical metals in the deep ocean.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.022
Threshold uncertainty score0.521

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.020
GPT teacher head0.296
Teacher spread0.276 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations4
Published2025
Admission routes1
Has abstractyes

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