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Record W4411091807 · doi:10.1002/prep.12090

Investigation on Hygroscopicity of Low Sensitive Gun Propellant Based on Ladder‐Structured Nitrocellulose

2025· article· en· W4411091807 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenuePropellants Explosives Pyrotechnics · 2025
Typearticle
Languageen
FieldEngineering
TopicEnergetic Materials and Combustion
Canadian institutionsMinistry of Education and Child Care
FundersNational Natural Science Foundation of China
KeywordsNitrocellulosePropellantMaterials scienceChemistryChemical engineeringAnalytical Chemistry (journal)ChromatographyOrganic chemistryEngineeringMembrane

Abstract

fetched live from OpenAlex

ABSTRACT Hygroscopicity plays a crucial role in the application of gun propellant. However, hygroscopicity of low sensitive gun propellant based on ladder‐structured nitrocellulose (LNC propellants) was not clear yet. In this work, moisture absorption behavior and hygroscopic mechanism of LNC propellants were studied by dynamic vapor sorption (DVS) instrument and molecular dynamics (MD) simulation. The DVS result shows that the capacity of moisture absorption for LNC propellants is obviously decreased by 60.60% (from 0.99% to 0.39% at RH of 50%) compared with propellants based on conventional nitrocellulose (NC), showing that moisture absorption behavior of low sensitive gun propellants can be inhibited well after the introduction of LNC. The Peleg absorption model provides a more accurate representation of the hygroscopic properties of LNC propellant, which can effectively predict the variation of moisture content throughout the moisture absorption process. Moreover, MD simulation results show that LNC has a weaker interaction with H 2 O molecule due to the grafting reaction of lots of hydroxyl group compared with NC, leading to lower hygroscopicity of LNC propellants. These results are expected to boost the practical application of low sensitive gun propellants containing LNC into the artillery.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.014
Threshold uncertainty score0.986

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.012
GPT teacher head0.196
Teacher spread0.184 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it