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Record W4411122154 · doi:10.1016/j.cej.2025.164550

Bioinspired trilayer poly(ε-caprolactone) scaffolds with native-like structures and mechanical property for heart valve constructs

2025· article· en· W4411122154 on OpenAlexafffund
Zeping Zhang, Rizheng Han, Xinqi Yu, Guixue Wang, Yunfeng Bai, Rui Yang, Tao Jin, Xing Zhang

Bibliographic record

VenueChemical Engineering Journal · 2025
Typearticle
Languageen
FieldMaterials Science
TopicElectrospun Nanofibers in Biomedical Applications
Canadian institutionsUniversity of Ottawa
FundersNational Key Research and Development Program of ChinaNatural Sciences and Engineering Research Council of CanadaMinistry of Science and Technology of the People's Republic of China
KeywordsCaprolactoneProperty (philosophy)Materials scienceNanotechnologyComposite materialPolymerizationPolymer

Abstract

fetched live from OpenAlex

Although valve replacement surgery is one of the primary treatments for patients with severe heart valve disease, current artificial valve options are lack of regenerative and remodeling potential, not suitable for pediatric and young patients. Inspired by the natural structures of heart valve leaflets, this study employed electrospinning technology to fabricate bioinspired trilayer poly(ε-caprolactone) scaffolds, aiming to replicate the microstructures and mechanical properties of native leaflets for tissue-engineered heart valves (TEHVs). Specifically, a collector with a honeycomb pattern was used to fabricate the middle layer, mimicking the spongiosa layer of native leaflets, while a roller collector was used to produce the orthogonal fiber alignment in the upper and lower layers. The prepared biomimetic tri-layered scaffold (BTS) not only mimicked the fiber alignment of native leaflets but also successfully reproduced the natural corrugation structure found in heart valve leaflets, generating a nonlinear stress-strain behavior resembling the “J-curve” observed in native leaflets. Furthermore, the anisotropic BTS exhibited elastic moduli (BTS-X: 12.50 ± 1.88 MPa; BTS-Y: 7.01 ± 1.12 MPa) and ultimate tensile strengths (UTS) (BTS-X: 8.09 ± 1.16 MPa; BTS-Y: 4.60 ± 0.75 MPa) in the orthogonal directions, close to those of native valve leaflets. In vitro cell culture demonstrated that BTS is non-cytotoxic, and cell alignment and proliferation behavior are influenced by the fiber orientation of the electrospun scaffold. Hemodynamic tests showed that the effective orifice area and regurgitation rate of the artificial valve can meet the requirements of the ISO 5840-2 standard. In summary, the tailored BTS mimicking natural microstructures exhibits isotropic mechanical properties similar to those of native leaflets, along with excellent biocompatibility, demonstrating great potential as a scaffold for TEHVs.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: none
Teacher disagreement score0.166
Threshold uncertainty score0.535

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.007
GPT teacher head0.229
Teacher spread0.222 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations7
Published2025
Admission routes2
Has abstractyes

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