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Mechanical performance and reinforcing potential of spun cellulose filaments in bio-based epoxy composites

2025· article· en· W4411957347 on OpenAlexaff
Hiba Ben Kahla, Luísa Rosenstock Völtz, Dickens O. Agumba, Jānis Vārna, Juha Salmela, Fredrik Forsberg, Henrik Lycksam, Kristiina Oksman

Bibliographic record

VenueComposites Part A Applied Science and Manufacturing · 2025
Typearticle
Languageen
FieldMaterials Science
TopicAdvanced Cellulose Research Studies
Canadian institutionsUniversity of Toronto
FundersWallenberg Wood Science CenterKnut och Alice Wallenbergs Stiftelse
KeywordsComposite materialMaterials scienceEpoxyCellulose

Abstract

fetched live from OpenAlex

Cellulose filaments with a unique microtape-like shape (width/thickness ratio ≈ 40) were studied for their potential as reinforcement in bio-epoxy resin with the hypothesis that their gross-sectional geometry would allow for efficient stress transfer and a higher transverse modulus. The microstructure of the spun filaments, orientation of the cellulose fibrils within them, and their mechanical properties were analyzed. Unidirectional (UD) composites with bio-epoxy resin were fabricated using vacuum infusion resulting in filament content of ≈ 23 vol% and low density 1.18 gcm −3 . Wide-angle X-ray scattering showed that the cellulose fibrils were relatively well aligned in the filament axis, having an orientation factor of 0.78. The axial filament modulus was measured to 33 GPa, the in-plane transverse modulus to 12 GPa and the axial strength was approx. 380 MPa. The longitudinal E-modulus of the UD composites was measured to 10 GPa and the strength to 120 MPa, both 3 times higher than the used bio-epoxy agreeing well with the estimated values. The transverse elongation at break of the UD composite was higher than typical values reported for glass-fiber epoxy composites, but the effect of filament shape on the transverse modulus was less significant than the predicted 4.5 GPa but still better than estimated for circular fibers. The lower property is likely due to the low filament content and the partially uneven in-plane filament arrangement. Simulations based on shear stress analysis suggest that the transverse properties of the UD composite could be improved by ensuring that the filament planes remain predominantly parallel in-plane during fabrication, and the overall mechanical properties could be improved by increasing the filament content.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.015
Threshold uncertainty score0.749

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.001
Scholarly communication0.0000.000
Open science0.0000.001
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.011
GPT teacher head0.253
Teacher spread0.241 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations1
Published2025
Admission routes1
Has abstractyes

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