Assessing the Acute and Chronic Effects of Palladium on <scp><i>Daphnia magna</i></scp> and the Influence of Natural Organic Matter
Bibliographic record
Abstract
ABSTRACT In recent decades, rising industrial demand for palladium (Pd), driven by its unique properties and affordability compared to other noble metals, has increased its environmental release into aquatic systems. This highlights the need to assess its effects on organisms, given the lack of standardized toxicity studies and regulations for this element. This study examines the acute and chronic impacts of Pd exposure on D. magna . Acute lethality was assessed over 48 h at measured Pd concentrations ranging from 2 to 110 μg/L, yielding an LC 50 of 52 ± 2 μg/L and an LC 10 of 33 ± 3 μg/L. The impact of natural organic matter from the Suwannee River on Pd lethality and bioaccumulation was also examined. No mortality occurred at DOC concentrations of 1, 2, 5, and 8 mg C/L, in contrast with the results obtained at 0.8 mg C/L, which resulted in an LC 50 of 74 ± 1 μg/L. Pd bioaccumulation decreased significantly with increasing DOC concentrations compared to controls. After 15 days of chronic exposure, offspring viability significantly declined, with an EC 50 of 1 ± 0.1 μg/L, alongside reductions in total broods per D. magna (EC 50 : 7 ± 2 μg/L). Parental dry weight also decreased significantly, though the timing of the first brood and weight‐normalized oxygen consumption rates remained unaffected across treatments. Parental survival was notably affected, with an LC 50 value of 14 ± 2 μg/L. These results emphasize Pd's potential for both lethal and sublethal effects, highlighting the need for environmental standards to protect aquatic life.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".