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Record W4412796628 · doi:10.1016/j.dental.2025.07.013

Effect of thickness and irradiance on the polymerization delay at the bottom surface of light-cured resin composites

2025· article· en· W4412796628 on OpenAlexafffund
Richard Bengt Price, Alex Gareau, B. D. MacNeil, D. Labrie, B.W. Darvell, Frederick A. Rueggeberg, Jeffrey W. Stansbury

Bibliographic record

VenueDental Materials · 2025
Typearticle
Languageen
FieldChemistry
TopicPhotopolymerization techniques and applications
Canadian institutionsDalhousie University
FundersRural Business-Cooperative ServiceResearch Nova ScotiaMitacsDalhousie University
KeywordsMaterials scienceIrradianceComposite materialPolymerizationResin compositeSurface (topology)Composite numberOpticsPolymerGeometry

Abstract

fetched live from OpenAlex

Objective To examine the effects of the resin-based composite (RBC) thickness and incident irradiance on the time delay after the light turns on before polymerization starts at the bottom surface of the RBC. Methods The degree of conversion (DC) was determined using Fourier-transform infrared spectroscopy (FT-IR) at a rate of 13 measurements per second. Six commercial RBCs were tested at three thicknesses (0.2, 2 and 4 mm) and four incident irradiance values (472–3985 mW/cm 2 ). Results There was a significant time delay before polymerization began at the bottom of each RBC. At 942 mW/cm 2 , representative of many current LCUs, this delay ranged from 0.12 to 1.11 s at the bottom of 2 mm of RBC. When the thickness was increased to 4 mm, even with an irradiance of 1969 mW/cm 2 , which represents high-power LCUs, the delay ranged from 0.12 to 5.17 s. The highest irradiance of 3985 mW/cm 2 did not fully overcome the inherent lag caused by the thickness of the RBC. At 3985 mW/cm 2 , PowerFlow and PowerFill had the shortest delay times of 0.09 s and 0.30 s, respectively, at the bottom of a 4 mm thick RBC. Significance The presence of a time delay before photo-cured RBCs start to polymerize at the bottom surfaces must now be addressed clinically and when calculating reaction rates.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.002
Threshold uncertainty score0.007

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.001
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0020.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.004
GPT teacher head0.245
Teacher spread0.241 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations2
Published2025
Admission routes2
Has abstractyes

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