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Record W4412891602 · doi:10.1016/j.bmcl.2025.130353

Design of a peripherally biased NPSR1 antagonist for neuropeptide S induced inflammation

2025· article· en· W4412891602 on OpenAlexaff
Kathleen J Berger, Kévin Leguay, F. Moreau, Benny K. K. Chan, Giovanni Martino, E. S. Cho, Nils Nordstrom, Sharon Sun, Elizabeth Franks, Joseph A. Mancini, Janek Szychowski, Oliver A. Kent

Bibliographic record

VenueBioorganic & Medicinal Chemistry Letters · 2025
Typearticle
Languageen
FieldNeuroscience
TopicNeuropeptides and Animal Physiology
Canadian institutionsFPInnovations
Fundersnot available
KeywordsInflammationChemistryPharmacologyImmunologyBiology

Abstract

fetched live from OpenAlex

Neuropeptide S (NPS) is a potent agonist for the GPCR receptor NPSR1, implicated in various physiological and pathological processes, including inflammation. NPSR1 gene polymorphisms have been linked to asthma, inflammatory bowel disease, and endometriosis. Activation of NPSR1 triggers signaling through Gαq and Gαs leading to activation of calcium and cAMP respectively, which induces the expression of pro-inflammatory cytokines. Given NPSR1 is widely expressed in the brain and modulates behavioral responses, the development of a non-brain-penetrant NPSR1 antagonist with favorable pharmacokinetics would represent a significant advancement. While promising NPSR1 antagonists like SHA-68R and NPSR-QA1 exist, suboptimal ADME profiles and/or brain penetrance limit pharmacological evaluation of NPSR1 peripheral inhibition. In the present study, a structure-activity relationship analysis of NPSR-QA1 led to the identification of two potent, peripherally restricted NPSR1 antagonists with favorable pharmacokinetic properties. NPSR-QA1 derivatives were screened for NPSR1 antagonism in cell-based calcium and cAMP signaling assays. Two lead compounds were identified that demonstrated sub-nanomolar potency, high solubility, decent unbound clearance, and low brain penetration in mice. In vitro assays using human fibroblasts with enforced expression of NPSR1 established that NPS triggered expression of pro-inflammatory markers IL-6, PTGS2, IL-20, and CXCL8, all of which were effectively inhibited by the lead compounds. Further, murine studies with zymosan-induced inflammation showed that NPSR1 antagonism significantly increased resident macrophages in the peritoneum and reduced TNF-α cytokine levels. These findings highlight the potential of NPSR1 antagonism to block inflammation without CNS side effects, advancing the development of NPSR1 antagonists as therapeutic agents for peripheral inflammation.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.002
Threshold uncertainty score0.007

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0020.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.038
GPT teacher head0.270
Teacher spread0.232 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2025
Admission routes1
Has abstractyes

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