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Record W4412925433 · doi:10.1093/petrology/egaf062

Diamond-Silicate-Sulphide-Oxide Textural Relationships in Diamondiferous Eclogites from the Kalahari Craton Revealed by 3D X-Ray Computed Tomography

2025· article· en· W4412925433 on OpenAlexaff
Geoffrey H. Howarth, Beth Kahle, P. E. Janney, Richard Kahle, Anton du Plessis, Stephen H. Richardson, John Gurney

Bibliographic record

VenueJournal of Petrology · 2025
Typearticle
Languageen
FieldEarth and Planetary Sciences
TopicGeological and Geochemical Analysis
Canadian institutionsOpal-Rt Technologies (Canada)
Fundersnot available
KeywordsGeologyEclogiteGeochemistrySilicateDiamondCratonKimberliteMineralogySeismologyMaterials scienceTectonicsMantle (geology)ChemistryMetallurgySubduction

Abstract

fetched live from OpenAlex

Abstract X-ray computed tomography (CT) scanning provides a non-destructive way to image diamonds within their host mantle rocks. The CT scans produce thousands of 2D slices, referred to here as pseudo-thin sections, allowing us to observe the textural relationships between diamonds and the surrounding minerals, such as silicates, oxides, and sulphides. In this study, we present CT scans of 18 diamond-bearing eclogites from three locations across the Kalahari craton. The scans reveal that the diamonds are mostly well-formed, step-faced crystals. These step-faced diamonds are associated with metasomatic textures, either forming in distinct veins that cut through the silicate minerals of the xenoliths or along the grain boundaries between garnet and clinopyroxene. The data suggest that diamonds typically form at the expense of garnet, indicating simultaneous garnet dissolution and diamond-friendly metasomatism. In some cases, diamonds appear in specific planes, though there is no visible evidence of the metasomatic minerals responsible for their formation. These instances may represent original diamond growth through metasomatic alteration of the eclogite, followed by recrystallization that erased signs of the earlier diamond-friendly event. We also find evidence of in situ diamond destruction due to metasomatic modification of the eclogites, linked to silicate- and sulphide-rich metasomatism through melt or fluid percolation along garnet–clinopyroxene grain boundaries. While sulphide-rich metasomatism is common in these eclogites, it does not show a clear spatial or temporal link to diamond-forming metasomatic events. Overall, the textural evidence suggests that these diamondiferous eclogites have experienced multiple stages of both diamond-forming and diamond-destructive metasomatism involving silicate and sulphide-rich fluids over their billions of years in the sub-continental lithospheric mantle.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.021
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.010
GPT teacher head0.200
Teacher spread0.190 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations1
Published2025
Admission routes1
Has abstractyes

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