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Record W4413439875 · doi:10.1016/j.ces.2025.122475

High-Rate Vacuum-Enhanced anaerobic Digestion: Performance, ammonia recovery and process kinetics

2025· article· en· W4413439875 on OpenAlexafffund
Ali Khadir, Eun-Kyung Jang, Domenico Santoro, John Walton, Ahmed Al‐Omari, Christopher Muller, Katherine Y. Bell, Wayne J. Parker, Martha J.M. Wells, George Nakhla

Bibliographic record

VenueChemical Engineering Science · 2025
Typearticle
Languageen
FieldEngineering
TopicAnaerobic Digestion and Biogas Production
Canadian institutionsUniversity of WaterlooWestern University
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsKineticsAnaerobic digestionAmmoniaAnaerobic exerciseChemistryProcess (computing)Pulp and paper industryChemical engineeringProcess engineeringBiochemistryMethaneComputer scienceBiologyEngineeringOrganic chemistryPhysics

Abstract

fetched live from OpenAlex

This study investigated the applicability of side-stream vacuum for intensification of anaerobic digestion (AD) at organic loading rates (OLRs) of 3.8–4.5 kgVS/m 3 /d (6.1–7.3 kgCOD/m 3 /d), and ammonia recovery at four times the OLR of a conventional AD. Initial operation showed a performance decline due to Methanosaeta dominance and its inability to resist vacuum, resulting in low methane yield (0.06 L/gCOD feed , 15 % COD destruction) and high SCOD accumulation (12 g/L). Methanosarcinaceae enrichment under vacuum restored stability, achieving 49 %–53 % VSS destruction. Ammonia inhibition was mitigated by 44 %–47 % TKN recovery through ex-situ vacuum stripping, maintaining ammonia concentrations below 1 gN/L, compared to a potential inhibitory level of > 4 gN/L without ex-situ vacuum. The dominance of Methanosarcinaceae and successful ammonia recovery corresponded with stable operation at four times the OLR of conventional digesters. Biokinetic studies revealed a 155 %–232 % improvement in biomass-specific acetoclastic methanogenic activity through ex-situ vacuum. Fluorescence excitation-emission matrix-parallel factor analysis showed accumulation of the slowly biodegradable fluorescing organic. High fermentative bacterial counts were maintained, with increased populations of DMER64 , Mesotoga , Synergistaceae , Clostridium_sensu_stricto_1 , Pelotomaculum, and Syntrophomonas , suggesting resistance to vacuum stress, while Smithella decreased.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.072
Threshold uncertainty score0.636

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.004
GPT teacher head0.192
Teacher spread0.188 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations2
Published2025
Admission routes2
Has abstractyes

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