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Record W4413876898 · doi:10.1021/acs.estlett.5c00678

Trifluoroacetic Acid in Australian Human Urine Samples

2025· article· en· W4413876898 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueEnvironmental Science & Technology Letters · 2025
Typearticle
Languageen
FieldEnvironmental Science
TopicPer- and polyfluoroalkyl substances research
Canadian institutionsUniversity of Guelph
FundersUniversity of QueenslandQueensland Health
KeywordsTrifluoroacetic acidUrineChromatographyChemistryBiochemistry

Abstract

fetched live from OpenAlex

Trifluoroacetic acid (TFA), a terminal degradation product of numerous industrial chemicals, pharmaceuticals, and pesticides, has been shown to be increasing in concentration in environmental media. However, very limited information is available on levels and trends in humans. TFA was analyzed in deidentified pathology urine samples from Australia, which were pooled by collection year, age, and sex using a direct-injection ion-chromatography method. TFA was detected in all samples ( n = 70 pools, 6040 individuals), ranging from 3.4 to 300 μg/L, with a median of 24 μg/L. Significantly higher concentrations were found in older (>45–60 and >60 years) compared to younger groups (>5–45 years). Concentrations increased with age in children (from <1 to <5 years). Mean concentrations from >5 to >60 years for 2012/2013, 2014/2015, and 2020/2021 did not differ significantly, suggesting that exposures have not changed over that period. The high detection frequency and relatively high concentrations found in this study indicate high chronic exposure to TFA in Australia, consistent with ubiquitous TFA in food, household dust, and drinking water reported in other countries. Many questions remain regarding trends over longer periods, variations with age, and sources of TFA exposure.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesScience and technology studies, Insufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.280
Threshold uncertainty score0.999

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0010.003
Science and technology studies0.0010.006
Scholarly communication0.0000.000
Open science0.0020.001
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0020.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.010
GPT teacher head0.268
Teacher spread0.257 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it