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A comparative economic assessment of freshwater versus chloralkali electrolysis for eMethanol production

2025· article· en· W4413901017 on OpenAlexaff
Arun Kumar Tiwari, Deóis UaCearnaigh, Dia Milani

Bibliographic record

VenueInternational Journal of Hydrogen Energy · 2025
Typearticle
Languageen
FieldEngineering
TopicExtraction and Separation Processes
Canadian institutionsLakes Environmental (Canada)
Fundersnot available
KeywordsProduction (economics)ElectrolysisEnvironmental scienceChemistryEconomicsMacroeconomics

Abstract

fetched live from OpenAlex

In recent years, renewable-powered eFuels syntheses have gained significant attention due to their potential to reduce the reliance on fossil fuels and consequently greenhouse gas (GHG) emissions. However, the cost of eFuels production is still a major concern and is mostly driven by two major components: the cost of non-fossil based carbon dioxide (CO 2 ) that is expected to be sourced from direct air capture (DAC) technology, and the cost of H 2 production from conventional freshwater electrolysis. This paper explores the substitution of freshwater electrolysis with saltwater electrolysis, which yields a product-basket of eMethanol (eMeOH), caustic soda, chlorine and desalinated water, which are feedstocks vital to modern industry. This improves the total revenue generated from the equipment and energy consumed by the system as compared to the Benchmark freshwater based eMeOH production. For the normalized production of ⁓1.0 tonne/hour (t/h) of eMeOH, this novel process route consumes ∼18 % more electricity than the Benchmark but also produces ∼6.8 t/h of chlorine gas and ∼7.7 t/h of caustic soda. Using the same price index to compare the processes, the gross revenue of the considered process route is estimated at ∼5290 USD/t-eMeOH product basket, exceeding by far the gross revenue calculated for the Benchmark freshwater based counterpart at ∼800 USD/t-eMeOH. Consequently, for every unit of energy consumed, the eMeOH-containing product basket produced through the chloralkali electrolysis route exhibits the capacity to generate 6.6 times more revenue than the Benchmark, and thus produces eMeOH at significantly lower net cost.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Simulation or modeling · Consensus signal: Simulation or modeling
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.004
Threshold uncertainty score0.019

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.001
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0000.001
Bibliometrics0.0020.002
Science and technology studies0.0000.000
Scholarly communication0.0010.001
Open science0.0010.001
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0030.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.019
GPT teacher head0.328
Teacher spread0.308 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designSimulation or modeling
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations2
Published2025
Admission routes1
Has abstractyes

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