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Record W4413997258 · doi:10.1016/j.jqsrt.2025.109650

Term energy analysis of iron monohydride (FeH)

2025· article· en· W4413997258 on OpenAlexafffund
Timothy Blackmore, D. W. Tokaryk

Bibliographic record

VenueJournal of Quantitative Spectroscopy and Radiative Transfer · 2025
Typearticle
Languageen
FieldMaterials Science
TopicHydrogen Storage and Materials
Canadian institutionsUniversity of New Brunswick
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsTerm (time)Environmental scienceAstrobiologyPhysicsAstronomy

Abstract

fetched live from OpenAlex

MARVEL software was used to perform a global fit on all FeH transitions available in the literature to create an optimized and comprehensive term energy list. The diverse types of data, data sources, and electronic transitions that were used for this fit are organized and tabulated. To improve the fit, inconsistencies in the F 4 Δ -X 4 Δ analysis published in 1987 were fixed using modern computation and visualization techniques. F 4 Δ -A 4 Π transitions were identified in spectra published in the Kitt Peak archive and added to the fit. Also, several laser excitation and Fourier transform spectrometer measurements taken in our lab were added, including those from the newly discovered I 4 Φ electronic state. The final term energy list and transition list are given in the supplementary material. • Iron monohydride transitions were analysed from 16 sources plus those we measured. • 5190 transitions were inputted into MARVEL to generate 1648 energy levels. • Transition assignments from previous literature were updated when necessary. • Updated term energies are significantly more consistent with all the transitions.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.083
Threshold uncertainty score0.556

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0010.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.012
GPT teacher head0.302
Teacher spread0.291 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2025
Admission routes2
Has abstractyes

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