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Record W4414105245 · doi:10.1016/j.optmat.2025.117511

Optical investigation and thermal stabilization of germanium-gallium-containing bismuthate glasses towards NIR-MIR applications

2025· article· en· W4414105245 on OpenAlexafffund
Hüseyin Can Çamiçi, Théo Guérineau, Sophie LaRochelle, Younès Messaddeq

Bibliographic record

VenueOptical Materials · 2025
Typearticle
Languageen
FieldMaterials Science
TopicGlass properties and applications
Canadian institutionsNatural Sciences and Engineering Research Council of Canada
FundersNatural Sciences and Engineering Research Council of CanadaCanada Excellence Research Chairs, Government of CanadaCanada Foundation for InnovationFonds de recherche du Québec – Nature et technologiesUniversité Laval
KeywordsDifferential scanning calorimetryThermal stabilityOptical fiberDopingRefractive indexGlass fiberCrystallizationFabricationMulti-mode optical fiberChalcogenide glass

Abstract

fetched live from OpenAlex

The progress in the utilization of heavy metal oxide glasses in mid-infrared photonic applications has been hindered by the complication of fabricating thermally stable glass compositions as well as optical fibers with acceptable optical losses. To overcome these obstacles, a range of BaO-Ga 2 O 3 -GeO 2 -Bi 2 O 3 glasses were fabricated by increasing the BaO content while decreasing Bi 2 O 3 . Differential scanning calorimetry studies revealed that the thermal stability of the glasses increases up to 27.5 mol% BaO at which the glass does not yield a crystallization peak even at very low heating rates. High linear and nonlinear refractive index of the glasses were also shown. Spectroscopic properties of the thermally most stable glass were investigated by various Er 3+ -doping content. The luminescence spectra and lifetime values showed suitable results, even with high doping content, for applications requiring optical signal amplification. A multimode optical fiber with an undoped core was drawn by rod-in-tube technique which yielded an optical loss of 10 dB/m for a 3-meter-long fiber. With appropriate precursor purification, glass dehydration and glass fabrication optimization steps, BaO-Ga 2 O 3 -GeO 2 -Bi 2 O 3 glasses are important alternatives to PbO-GeO 2 and TeO 2 -based glasses for MIR applications in optical fiber or bulk glass form.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.003

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.018
GPT teacher head0.263
Teacher spread0.244 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations1
Published2025
Admission routes2
Has abstractyes

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