MétaCan
Menu
Back to cohort
Record W4414153075 · doi:10.1016/j.cis.2025.103666

New horizons in synthesis, functionalization, and deposition of advanced materials using multifunctional organic alkalizers

2025· review· en· W4414153075 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueAdvances in Colloid and Interface Science · 2025
Typereview
Languageen
FieldMaterials Science
TopicConducting polymers and applications
Canadian institutionsMcMaster University
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsFabricationDeposition (geology)Supramolecular chemistryPolymerSupercapacitorNanoparticleNanocrystalSurface modificationSupramolecular polymers

Abstract

fetched live from OpenAlex

This review describes new strategies in the use of multifunctional organic alkalizers (OA) for the fabrication of advanced functional materials. OA facilitate solubilization and delivery of poorly solubilized drugs through the formation of drug-OA complexes and supramolecular gels. OA are applied for the synthesis of materials for biomedical, energy storage, catalytic, photovoltaic, sensor, and electronic applications. The synthesis of nanocrystals with controlled size, crystal phase, shape, and tunable facets in the presence of OA-capping agents is described. The synthesis of materials for energy storage in batteries and supercapacitors using OA or adding OA to electrolytes results in improved power-energy characteristics and cyclic stability. The multifunctional OA allow the fabrication of advanced bioceramics and biocements, novel supramolecular gels, surface modification of materials for advanced catalytic, water purification, and sensor applications. Various challenges in the dispersion of functional nanoparticles are addressed for colloidal manufacturing. The ability of the OA to form supramolecular gels paves the way for the development of novel functional materials. New strategies in the solubilization of polymers and other functional materials open an avenue for the development of advanced electrodeposition methods for the deposition of polymer and composite films. Fundamental mechanisms and future research avenues are described.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Review · Consensus signal: Review
Teacher disagreement score0.258
Threshold uncertainty score0.835

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.001
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.020
GPT teacher head0.336
Teacher spread0.316 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it