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Record W4414162783 · doi:10.1002/cbdv.202501604

Structure‐Photoprotective Capacity Relationship of Phenolic Hydroxyl, Methoxy, and Ethenyl Linker Moieties of Phenolic Acids

2025· article· en· W4414162783 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueChemistry & Biodiversity · 2025
Typearticle
Languageen
FieldMedicine
TopicSynthesis of Organic Compounds
Canadian institutionsUniversité de Moncton
FundersNatural Sciences and Engineering Research Council of CanadaNew Brunswick Innovation FoundationUniversité de Moncton
KeywordsPolyphenolPhotoprotectionPhenolic acidLinkerCytotoxicityp-Coumaric acid

Abstract

fetched live from OpenAlex

As constituents of many plants, polyphenols can neutralize free radicals. By inactivating free radicals, skin homeostasis can be restored, which may prevent further damage and premature skin aging. To prevent the damage caused by UV exposure, photoprotection is becoming increasingly important. Plants known to be rich in polyphenols have been investigated for their use as sunscreens. The synergistic effect, which is due to the specific composition of plant extracts, is a disadvantage for applications such as large-scale sunscreens. The great diversity of polyphenols present in such plants can be an obstacle to the identification of the most effective polyphenol families. Investigating polyphenol families by family could provide more information than plant extracts with various polyphenols and a multitude of other molecules. In this study, we focused on the phenolic acids subclass. Eleven phenolic acids have been investigated for their potential use as sunscreen. According to its Boots Star rating or to its critical wavelength, p-coumaric acid shows good potential for use as a sunscreen especially for exposure to UVB radiation. The absence of cytotoxicity of coumaric acid on normal human dermal fibroblasts (NHDF), even at high concentrations, further validates the potential use of this acid in sunscreen formulations.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.096
Threshold uncertainty score0.797

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.001
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.021
GPT teacher head0.243
Teacher spread0.222 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it